{"title":"A Novel Apparent Permeability Model for Shale Matrix Derived under the Framework of the Energy Conservation Law","authors":"Shuai Chen*, Xulin Peng and Haoran Xu, ","doi":"10.1021/acsomega.4c0835510.1021/acsomega.4c08355","DOIUrl":null,"url":null,"abstract":"<p >With the rapid development of fracturing technology, unconventional oil and gas resources, such as shale oil and gas, are gradually becoming mainstream energy consumption. However, owing to the complex microstructure in shale reservoirs, it is still a challenge to accurately describe the gas transport characteristics in shale and predict the changes in its permeability. Gas transport in the shale matrix does not always fall into the continuum hypothesis of the Navier–Stokes equation; namely, when the Knudsen number increases, the proportion of the continuum flow is smaller. The gas extraction process is a nonlinear process under the alternate influence of different transport mechanisms and different microscale effects. In this work, the capillary tube space is divided into three different flow zones, and under the law of energy conservation, this study first establishes a bulk gas transport model of shale, which couples continuum flow and Knudsen diffusion. Also, based on the bulk gas transport model, an apparent permeability model of shale is developed by further considering the influence of surface diffusion, gas adsorption, and effective stress. In the apparent permeability model, this paper develops a slip velocity model, which is composed of gas coverage degree as a weight coefficient coupling both Knudsen diffusion velocity and surface diffusion velocity. It is found that the results calculated by the model fit well with the real observation. Moreover, compared with other apparent permeability models, the accuracy of the proposed model improves.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"10 12","pages":"11861–11872 11861–11872"},"PeriodicalIF":3.7000,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsomega.4c08355","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Omega","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsomega.4c08355","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
With the rapid development of fracturing technology, unconventional oil and gas resources, such as shale oil and gas, are gradually becoming mainstream energy consumption. However, owing to the complex microstructure in shale reservoirs, it is still a challenge to accurately describe the gas transport characteristics in shale and predict the changes in its permeability. Gas transport in the shale matrix does not always fall into the continuum hypothesis of the Navier–Stokes equation; namely, when the Knudsen number increases, the proportion of the continuum flow is smaller. The gas extraction process is a nonlinear process under the alternate influence of different transport mechanisms and different microscale effects. In this work, the capillary tube space is divided into three different flow zones, and under the law of energy conservation, this study first establishes a bulk gas transport model of shale, which couples continuum flow and Knudsen diffusion. Also, based on the bulk gas transport model, an apparent permeability model of shale is developed by further considering the influence of surface diffusion, gas adsorption, and effective stress. In the apparent permeability model, this paper develops a slip velocity model, which is composed of gas coverage degree as a weight coefficient coupling both Knudsen diffusion velocity and surface diffusion velocity. It is found that the results calculated by the model fit well with the real observation. Moreover, compared with other apparent permeability models, the accuracy of the proposed model improves.
ACS OmegaChemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍:
ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.