Conjugated microporous polymer containing pyrene and Dibenzo[g,p]chrysene moieties as a luminescent powerhouse for multi-target sensing and environmental safety

IF 4.8 3区材料科学 Q1 CHEMISTRY, APPLIED

Microporous and Mesoporous Materials Pub Date : 2025-03-25 DOI:10.1016/j.micromeso.2025.113620

Mohamed Gamal Mohamed , Abdul Basit , Manivannan Madhu , K. Aravinthkumar , Awad I. Said , Devaraj Manoj , Wei-Lung Tseng , Shiao-Wei Kuo

{"title":"Conjugated microporous polymer containing pyrene and Dibenzo[g,p]chrysene moieties as a luminescent powerhouse for multi-target sensing and environmental safety","authors":"Mohamed Gamal Mohamed , Abdul Basit , Manivannan Madhu , K. Aravinthkumar , Awad I. Said , Devaraj Manoj , Wei-Lung Tseng , Shiao-Wei Kuo","doi":"10.1016/j.micromeso.2025.113620","DOIUrl":null,"url":null,"abstract":"<div><div>Conjugated microporous polymers (CMPs) have emerged as highly versatile materials, garnering significant attention in recent years due to their unique structural and functional properties. This study presents the development and synthesis of a CMP based on Py-TBNBZ, achieved via a well-established [4 + 4] Schiff base reaction. The reaction involves two primary building blocks: 4,4′,4″,4‴-(pyrene-1,3,6,8-tetrayl)tetrabenzaldehyde (PyBZ-4CHO) and 4,4′,4″,4‴-(dibenzo[g,p]chrysene-2,7,10,15-tetrayl)tetraaniline (TBNBZ-4NH2). The structural and morphological characteristics of the synthesized Py-TBNBZ CMP material were systematically analyzed using advanced experimental techniques, confirming the successful formation of a robust framework. The Py-TBNBZ CMP prepared in this study showed a BET surface area (SBET) of 497 m2 g−1. Thermal analysis indicated a decomposition temperature (Td10) of 476 °C and a notable char yield of 74 wt%, as confirmed through BET and TGA measurements. One of the most notable features of the Py-TBNBZ CMP is its strong fluorescence, which enabled its application in chemical sensing. The material exhibited exceptional sensitivity and selectivity, allowing for the detection of K+ and Fe2+ ions and precise pH monitoring over a broad pH range (pH 2–10). The underlying sensing mechanisms were investigated and elucidated. Additionally, the Py-TBNBZ CMP demonstrated remarkable adsorption capabilities for hazardous gas vapors, including ammonia (NH3) and hydrogen chloride (HCl), underscoring its potential for environmental remediation. The flexibility of the Py-TBNBZ CMP distinguishes it from other CMPs and porous materials, enabling superior performance, enhanced applicability, and improved operational efficiency. This work highlights the advanced capabilities of Py-TBNBZ CMP and contributes to the ongoing development of innovative materials for adsorption, environmental protection, and next-generation sensing technologies.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"391 ","pages":"Article 113620"},"PeriodicalIF":4.8000,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microporous and Mesoporous Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387181125001349","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}

引用次数: 0

Abstract

Conjugated microporous polymers (CMPs) have emerged as highly versatile materials, garnering significant attention in recent years due to their unique structural and functional properties. This study presents the development and synthesis of a CMP based on Py-TBNBZ, achieved via a well-established [4 + 4] Schiff base reaction. The reaction involves two primary building blocks: 4,4′,4″,4‴-(pyrene-1,3,6,8-tetrayl)tetrabenzaldehyde (PyBZ-4CHO) and 4,4′,4″,4‴-(dibenzo[g,p]chrysene-2,7,10,15-tetrayl)tetraaniline (TBNBZ-4NH₂). The structural and morphological characteristics of the synthesized Py-TBNBZ CMP material were systematically analyzed using advanced experimental techniques, confirming the successful formation of a robust framework. The Py-TBNBZ CMP prepared in this study showed a BET surface area (S_BET) of 497 m² g⁻¹. Thermal analysis indicated a decomposition temperature (T_d10) of 476 °C and a notable char yield of 74 wt%, as confirmed through BET and TGA measurements. One of the most notable features of the Py-TBNBZ CMP is its strong fluorescence, which enabled its application in chemical sensing. The material exhibited exceptional sensitivity and selectivity, allowing for the detection of K⁺ and Fe²⁺ ions and precise pH monitoring over a broad pH range (pH 2–10). The underlying sensing mechanisms were investigated and elucidated. Additionally, the Py-TBNBZ CMP demonstrated remarkable adsorption capabilities for hazardous gas vapors, including ammonia (NH₃) and hydrogen chloride (HCl), underscoring its potential for environmental remediation. The flexibility of the Py-TBNBZ CMP distinguishes it from other CMPs and porous materials, enabling superior performance, enhanced applicability, and improved operational efficiency. This work highlights the advanced capabilities of Py-TBNBZ CMP and contributes to the ongoing development of innovative materials for adsorption, environmental protection, and next-generation sensing technologies.

Abstract Image

查看原文本刊更多论文

含有芘和二苯并[g,p]菊烯分子的共轭微孔聚合物是用于多目标传感和环境安全的发光动力源

共轭微孔聚合物（cmp）作为一种用途广泛的材料，由于其独特的结构和功能特性，近年来受到了广泛的关注。本研究介绍了基于Py-TBNBZ的CMP的开发和合成，通过建立[4 + 4]希夫碱反应实现。该反应涉及两个主要组成部分：4,4 ',4″，4′-（芘-1,3,6,8-四基）四苯甲醛（PyBZ-4CHO）和4,4 ',4″，4′-（二苯并[g，p]芘-2,7,10,15-四基）四苯胺（TBNBZ-4NH2）。利用先进的实验技术系统分析了合成的Py-TBNBZ CMP材料的结构和形态特征，证实了成功形成了坚固的框架。本研究制备的Py-TBNBZ CMP的BET表面积（SBET）为497 m2 g−1。热分析表明，分解温度（Td10）为476°C，通过BET和TGA测量证实，焦炭产率为74%。Py-TBNBZ CMP最显著的特点之一是其强烈的荧光，使其能够应用于化学传感。该材料表现出优异的灵敏度和选择性，可以检测K+和Fe2+离子，并在较宽的pH范围内（pH 2-10）进行精确的pH监测。研究并阐明了潜在的传感机制。此外，Py-TBNBZ CMP对包括氨（NH3）和氯化氢（HCl）在内的有害气体蒸汽具有显著的吸附能力，强调了其环境修复的潜力。Py-TBNBZ CMP的灵活性使其与其他CMP和多孔材料区别开来，具有卓越的性能，增强的适用性和提高的操作效率。这项工作突出了Py-TBNBZ CMP的先进能力，并有助于持续开发用于吸附，环保和下一代传感技术的创新材料。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Microporous and Mesoporous Materials 化学-材料科学：综合

CiteScore

10.70

自引率

5.80%

发文量

649

审稿时长

26 days

期刊介绍： Microporous and Mesoporous Materials covers novel and significant aspects of porous solids classified as either microporous (pore size up to 2 nm) or mesoporous (pore size 2 to 50 nm). The porosity should have a specific impact on the material properties or application. Typical examples are zeolites and zeolite-like materials, pillared materials, clathrasils and clathrates, carbon molecular sieves, ordered mesoporous materials, organic/inorganic porous hybrid materials, or porous metal oxides. Both natural and synthetic porous materials are within the scope of the journal. Topics which are particularly of interest include: All aspects of natural microporous and mesoporous solids The synthesis of crystalline or amorphous porous materials The physico-chemical characterization of microporous and mesoporous solids, especially spectroscopic and microscopic The modification of microporous and mesoporous solids, for example by ion exchange or solid-state reactions All topics related to diffusion of mobile species in the pores of microporous and mesoporous materials Adsorption (and other separation techniques) using microporous or mesoporous adsorbents Catalysis by microporous and mesoporous materials Host/guest interactions Theoretical chemistry and modelling of host/guest interactions All topics related to the application of microporous and mesoporous materials in industrial catalysis, separation technology, environmental protection, electrochemistry, membranes, sensors, optical devices, etc.