Enhanced Methods for the Undecachlorination of [HCB11H11]- and Syntheses of [XCB11¬Cl11]- from [HCB11¬Cl11]- (X = Cl, Br, I, NH2)

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-03-28 DOI:10.1039/d4dt03033h

Jack P. Raker, Jovanny J. Contreras, S. Olivia Gunther, Oleg V. Ozerov

引用次数: 0

Abstract

Utilizing SbCl3/SbCl5 mixtures at reflux, or of TCCA in a solid-solid reaction at 200 °C (with properly described precautions) are described as reliable and convenient procedures for the conversion of [HCB11H11]- into [HCB11Cl11]-. Procedures for the derivatizaion of the carbon vertex of [HCB11Cl11]- to prepare [XCB11Cl11]- salts (X = Cl, Br, I, NH2) are also formulated.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.