Non-Fickian mesoscopic modeling of sorption and permeation in polymer nanocomposite membranes

IF 3.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL
AIChE Journal Pub Date : 2025-03-28 DOI:10.1002/aic.18841
Youness El Rhali, Ali El Afif
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Key dimensionless parameters are crucial to the analysis: structure-mixing constant <span data-altimg=\"/cms/asset/3b2fbdbf-0483-4b66-ad98-22797f4b02df/aic18841-math-0001.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0001\" display=\"inline\" location=\"graphic/aic18841-math-0001.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>g</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {g}_{\\mathrm{m}} $$</annotation>\n</semantics></math>, diffusion Deborah number <span data-altimg=\"/cms/asset/cd41a561-13e1-4f5e-97a1-f209880ccc04/aic18841-math-0002.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0002\" display=\"inline\" location=\"graphic/aic18841-math-0002.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>De</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {\\mathrm{De}}_{\\mathrm{m}} $$</annotation>\n</semantics></math>, nanofillers content <span data-altimg=\"/cms/asset/45b4fb54-c20b-4307-9aba-4680b1532916/aic18841-math-0003.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0003\" display=\"inline\" location=\"graphic/aic18841-math-0003.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>wt</mi>\n<mo>%</mo>\n</mrow>\n$$ \\mathrm{wt}\\% $$</annotation>\n</semantics></math> and aspect ratio <span data-altimg=\"/cms/asset/737eb9bc-a2e0-4806-b8df-a32d9bf1dfe3/aic18841-math-0004.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0004\" display=\"inline\" location=\"graphic/aic18841-math-0004.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi mathvariant=\"normal\">α</mi>\n</mrow>\n$$ \\upalpha $$</annotation>\n</semantics></math>, and orientation parameter. Numerical simulations demonstrate their effects on mass uptake, concentration, conformation, local and accumulated stresses, and permeation fluxes. Non-Fickian diffusion arises as <span data-altimg=\"/cms/asset/fb3acbad-80aa-4c12-970c-e1b55227711f/aic18841-math-0005.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0005\" display=\"inline\" location=\"graphic/aic18841-math-0005.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>De</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {\\mathrm{De}}_{\\mathrm{m}} $$</annotation>\n</semantics></math> approaches unity. The maximum stress decreases with <span data-altimg=\"/cms/asset/c2e7a4a5-6ec8-4bce-b9ef-74e3b9347770/aic18841-math-0006.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0006\" display=\"inline\" location=\"graphic/aic18841-math-0006.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>g</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {g}_{\\mathrm{m}} $$</annotation>\n</semantics></math> and <span data-altimg=\"/cms/asset/c74dd74c-6c6b-4d40-be2f-a4dd38a3b0f1/aic18841-math-0007.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0007\" display=\"inline\" location=\"graphic/aic18841-math-0007.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>α</mi>\n</mrow>\n$$ \\alpha $$</annotation>\n</semantics></math>, but increases with <span data-altimg=\"/cms/asset/5746117a-d228-4787-936c-813c7293c593/aic18841-math-0008.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0008\" display=\"inline\" location=\"graphic/aic18841-math-0008.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>De</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {\\mathrm{De}}_{\\mathrm{m}} $$</annotation>\n</semantics></math> or <span data-altimg=\"/cms/asset/85a642f6-6ad5-4d16-8693-370f5ae364a3/aic18841-math-0009.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0009\" display=\"inline\" location=\"graphic/aic18841-math-0009.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>wt</mi>\n<mo>%</mo>\n</mrow>\n$$ \\mathrm{wt}\\% $$</annotation>\n</semantics></math>. The permeation time lag increases with <span data-altimg=\"/cms/asset/e9c36e87-2164-47e9-ba17-22fd86826c49/aic18841-math-0010.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0010\" display=\"inline\" location=\"graphic/aic18841-math-0010.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>g</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {g}_{\\mathrm{m}} $$</annotation>\n</semantics></math>, <span data-altimg=\"/cms/asset/7a33a079-cb84-41ad-8212-e2b63e9fc6ac/aic18841-math-0011.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0011\" display=\"inline\" location=\"graphic/aic18841-math-0011.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>De</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n<mo>,</mo>\n</mrow>\n$$ {\\mathrm{De}}_{\\mathrm{m}}, $$</annotation>\n</semantics></math> <span data-altimg=\"/cms/asset/84576a4a-d40b-4823-b1d3-86eb92bb4c4b/aic18841-math-0012.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0012\" display=\"inline\" location=\"graphic/aic18841-math-0012.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>α</mi>\n</mrow>\n$$ \\alpha $$</annotation>\n</semantics></math>, and <span data-altimg=\"/cms/asset/6c380bc1-3a0d-4b67-850a-f1d79ba0cb41/aic18841-math-0013.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0013\" display=\"inline\" location=\"graphic/aic18841-math-0013.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>wt</mi>\n<mo>%</mo>\n</mrow>\n$$ \\mathrm{wt}\\% $$</annotation>\n</semantics></math>. The model's predictions show good agreement with sorption and permeation data.","PeriodicalId":120,"journal":{"name":"AIChE Journal","volume":"26 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"AIChE Journal","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/aic.18841","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0

Abstract

To investigate the interactions among nanoscale effects, viscoelasticity, and diffusion in polymer nanocomposite membranes, we have developed a non-Fickian mesoscopic model that describes the dynamics of penetrant concentration and the polymer conformation tensor. The model consists of nonlinear governing equations, supplemented by an expression for internal stresses. Key dimensionless parameters are crucial to the analysis: structure-mixing constant g m $$ {g}_{\mathrm{m}} $$ , diffusion Deborah number De m $$ {\mathrm{De}}_{\mathrm{m}} $$ , nanofillers content wt % $$ \mathrm{wt}\% $$ and aspect ratio α $$ \upalpha $$ , and orientation parameter. Numerical simulations demonstrate their effects on mass uptake, concentration, conformation, local and accumulated stresses, and permeation fluxes. Non-Fickian diffusion arises as De m $$ {\mathrm{De}}_{\mathrm{m}} $$ approaches unity. The maximum stress decreases with g m $$ {g}_{\mathrm{m}} $$ and α $$ \alpha $$ , but increases with De m $$ {\mathrm{De}}_{\mathrm{m}} $$ or wt % $$ \mathrm{wt}\% $$ . The permeation time lag increases with g m $$ {g}_{\mathrm{m}} $$ , De m , $$ {\mathrm{De}}_{\mathrm{m}}, $$ α $$ \alpha $$ , and wt % $$ \mathrm{wt}\% $$ . The model's predictions show good agreement with sorption and permeation data.
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来源期刊
AIChE Journal
AIChE Journal 工程技术-工程:化工
CiteScore
7.10
自引率
10.80%
发文量
411
审稿时长
3.6 months
期刊介绍: The AIChE Journal is the premier research monthly in chemical engineering and related fields. This peer-reviewed and broad-based journal reports on the most important and latest technological advances in core areas of chemical engineering as well as in other relevant engineering disciplines. To keep abreast with the progressive outlook of the profession, the Journal has been expanding the scope of its editorial contents to include such fast developing areas as biotechnology, electrochemical engineering, and environmental engineering. The AIChE Journal is indeed the global communications vehicle for the world-renowned researchers to exchange top-notch research findings with one another. Subscribing to the AIChE Journal is like having immediate access to nine topical journals in the field. Articles are categorized according to the following topical areas: Biomolecular Engineering, Bioengineering, Biochemicals, Biofuels, and Food Inorganic Materials: Synthesis and Processing Particle Technology and Fluidization Process Systems Engineering Reaction Engineering, Kinetics and Catalysis Separations: Materials, Devices and Processes Soft Materials: Synthesis, Processing and Products Thermodynamics and Molecular-Scale Phenomena Transport Phenomena and Fluid Mechanics.
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