{"title":"Non-Fickian mesoscopic modeling of sorption and permeation in polymer nanocomposite membranes","authors":"Youness El Rhali, Ali El Afif","doi":"10.1002/aic.18841","DOIUrl":null,"url":null,"abstract":"To investigate the interactions among nanoscale effects, viscoelasticity, and diffusion in polymer nanocomposite membranes, we have developed a non-Fickian mesoscopic model that describes the dynamics of penetrant concentration and the polymer conformation tensor. The model consists of nonlinear governing equations, supplemented by an expression for internal stresses. Key dimensionless parameters are crucial to the analysis: structure-mixing constant <span data-altimg=\"/cms/asset/3b2fbdbf-0483-4b66-ad98-22797f4b02df/aic18841-math-0001.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0001\" display=\"inline\" location=\"graphic/aic18841-math-0001.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>g</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {g}_{\\mathrm{m}} $$</annotation>\n</semantics></math>, diffusion Deborah number <span data-altimg=\"/cms/asset/cd41a561-13e1-4f5e-97a1-f209880ccc04/aic18841-math-0002.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0002\" display=\"inline\" location=\"graphic/aic18841-math-0002.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>De</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {\\mathrm{De}}_{\\mathrm{m}} $$</annotation>\n</semantics></math>, nanofillers content <span data-altimg=\"/cms/asset/45b4fb54-c20b-4307-9aba-4680b1532916/aic18841-math-0003.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0003\" display=\"inline\" location=\"graphic/aic18841-math-0003.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>wt</mi>\n<mo>%</mo>\n</mrow>\n$$ \\mathrm{wt}\\% $$</annotation>\n</semantics></math> and aspect ratio <span data-altimg=\"/cms/asset/737eb9bc-a2e0-4806-b8df-a32d9bf1dfe3/aic18841-math-0004.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0004\" display=\"inline\" location=\"graphic/aic18841-math-0004.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi mathvariant=\"normal\">α</mi>\n</mrow>\n$$ \\upalpha $$</annotation>\n</semantics></math>, and orientation parameter. Numerical simulations demonstrate their effects on mass uptake, concentration, conformation, local and accumulated stresses, and permeation fluxes. Non-Fickian diffusion arises as <span data-altimg=\"/cms/asset/fb3acbad-80aa-4c12-970c-e1b55227711f/aic18841-math-0005.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0005\" display=\"inline\" location=\"graphic/aic18841-math-0005.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>De</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {\\mathrm{De}}_{\\mathrm{m}} $$</annotation>\n</semantics></math> approaches unity. The maximum stress decreases with <span data-altimg=\"/cms/asset/c2e7a4a5-6ec8-4bce-b9ef-74e3b9347770/aic18841-math-0006.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0006\" display=\"inline\" location=\"graphic/aic18841-math-0006.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>g</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {g}_{\\mathrm{m}} $$</annotation>\n</semantics></math> and <span data-altimg=\"/cms/asset/c74dd74c-6c6b-4d40-be2f-a4dd38a3b0f1/aic18841-math-0007.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0007\" display=\"inline\" location=\"graphic/aic18841-math-0007.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>α</mi>\n</mrow>\n$$ \\alpha $$</annotation>\n</semantics></math>, but increases with <span data-altimg=\"/cms/asset/5746117a-d228-4787-936c-813c7293c593/aic18841-math-0008.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0008\" display=\"inline\" location=\"graphic/aic18841-math-0008.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>De</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {\\mathrm{De}}_{\\mathrm{m}} $$</annotation>\n</semantics></math> or <span data-altimg=\"/cms/asset/85a642f6-6ad5-4d16-8693-370f5ae364a3/aic18841-math-0009.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0009\" display=\"inline\" location=\"graphic/aic18841-math-0009.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>wt</mi>\n<mo>%</mo>\n</mrow>\n$$ \\mathrm{wt}\\% $$</annotation>\n</semantics></math>. The permeation time lag increases with <span data-altimg=\"/cms/asset/e9c36e87-2164-47e9-ba17-22fd86826c49/aic18841-math-0010.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0010\" display=\"inline\" location=\"graphic/aic18841-math-0010.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>g</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n</mrow>\n$$ {g}_{\\mathrm{m}} $$</annotation>\n</semantics></math>, <span data-altimg=\"/cms/asset/7a33a079-cb84-41ad-8212-e2b63e9fc6ac/aic18841-math-0011.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0011\" display=\"inline\" location=\"graphic/aic18841-math-0011.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<msub>\n<mi>De</mi>\n<mi mathvariant=\"normal\">m</mi>\n</msub>\n<mo>,</mo>\n</mrow>\n$$ {\\mathrm{De}}_{\\mathrm{m}}, $$</annotation>\n</semantics></math> <span data-altimg=\"/cms/asset/84576a4a-d40b-4823-b1d3-86eb92bb4c4b/aic18841-math-0012.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0012\" display=\"inline\" location=\"graphic/aic18841-math-0012.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>α</mi>\n</mrow>\n$$ \\alpha $$</annotation>\n</semantics></math>, and <span data-altimg=\"/cms/asset/6c380bc1-3a0d-4b67-850a-f1d79ba0cb41/aic18841-math-0013.png\"></span><math altimg=\"urn:x-wiley:00011541:media:aic18841:aic18841-math-0013\" display=\"inline\" location=\"graphic/aic18841-math-0013.png\" overflow=\"scroll\">\n<semantics>\n<mrow>\n<mi>wt</mi>\n<mo>%</mo>\n</mrow>\n$$ \\mathrm{wt}\\% $$</annotation>\n</semantics></math>. The model's predictions show good agreement with sorption and permeation data.","PeriodicalId":120,"journal":{"name":"AIChE Journal","volume":"26 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"AIChE Journal","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/aic.18841","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
To investigate the interactions among nanoscale effects, viscoelasticity, and diffusion in polymer nanocomposite membranes, we have developed a non-Fickian mesoscopic model that describes the dynamics of penetrant concentration and the polymer conformation tensor. The model consists of nonlinear governing equations, supplemented by an expression for internal stresses. Key dimensionless parameters are crucial to the analysis: structure-mixing constant , diffusion Deborah number , nanofillers content and aspect ratio , and orientation parameter. Numerical simulations demonstrate their effects on mass uptake, concentration, conformation, local and accumulated stresses, and permeation fluxes. Non-Fickian diffusion arises as approaches unity. The maximum stress decreases with and , but increases with or . The permeation time lag increases with , , and . The model's predictions show good agreement with sorption and permeation data.
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