{"title":"Investigation on the Ageing Behaviour of High-Modulus Modified Bitumen Based on Rheological and Chemical Approaches.","authors":"Xuemao Feng, Xin Li, Mingchen Li, Liping Liu, Zhenbang Cheng, Zhanchuang Han","doi":"10.3390/ma18061332","DOIUrl":null,"url":null,"abstract":"<p><p>With outstanding resistance for permanent deformation, high-modulus modified bitumen (HMB) has garnered widespread attention in recent years and has been employed in the construction of bitumen pavements across various regions. However, limited research exists on the ageing behaviour of HMB, and conventional short-term ageing protocols for bitumen may not be applicable to HMB due to its exceptionally high viscosity. Therefore, this study aims to assess the ageing behaviour of HMB and propose a suitable short-term ageing process for HMB utilizing dynamic shear rheometer (DSR) and gel permeation chromatography (GPC) approaches. For comparison purposes, the ageing behaviour of a type of SBS-modified bitumen and a kind of base bitumen were also analyzed. Initially, the study involved a comparison of the properties of bitumen subjected to short-term ageing at various temperatures and those of bitumen within mixtures undergoing short-term oven ageing tests. Subsequently, both the chemical and rheological properties of bitumen under diverse ageing conditions were examined. Finally, investigations were conducted to establish relationships between rheological properties and the molecular weight distribution of HMB. The reported results indicate that the suggested ageing temperature for the thin-film oven test (TFOT) should be increased to 193 °C for HMB, achieving a more accurate simulation of short-term ageing in HMB mixtures during on-site mixing, transport, and paving processes. Compared to base bitumen and SBS-modified bitumen, HMB exhibits superior ageing resistance. Furthermore, the molecular weight distribution of HMB is strongly correlated with its rheological properties. This correlation offers a promising approach to predict the rheological properties of bitumen in HMB mixtures by directly analyzing the chemical molecular weight distribution of the binders, thereby eliminating the need for an extraction process.</p>","PeriodicalId":18281,"journal":{"name":"Materials","volume":"18 6","pages":""},"PeriodicalIF":3.1000,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11943581/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.3390/ma18061332","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
With outstanding resistance for permanent deformation, high-modulus modified bitumen (HMB) has garnered widespread attention in recent years and has been employed in the construction of bitumen pavements across various regions. However, limited research exists on the ageing behaviour of HMB, and conventional short-term ageing protocols for bitumen may not be applicable to HMB due to its exceptionally high viscosity. Therefore, this study aims to assess the ageing behaviour of HMB and propose a suitable short-term ageing process for HMB utilizing dynamic shear rheometer (DSR) and gel permeation chromatography (GPC) approaches. For comparison purposes, the ageing behaviour of a type of SBS-modified bitumen and a kind of base bitumen were also analyzed. Initially, the study involved a comparison of the properties of bitumen subjected to short-term ageing at various temperatures and those of bitumen within mixtures undergoing short-term oven ageing tests. Subsequently, both the chemical and rheological properties of bitumen under diverse ageing conditions were examined. Finally, investigations were conducted to establish relationships between rheological properties and the molecular weight distribution of HMB. The reported results indicate that the suggested ageing temperature for the thin-film oven test (TFOT) should be increased to 193 °C for HMB, achieving a more accurate simulation of short-term ageing in HMB mixtures during on-site mixing, transport, and paving processes. Compared to base bitumen and SBS-modified bitumen, HMB exhibits superior ageing resistance. Furthermore, the molecular weight distribution of HMB is strongly correlated with its rheological properties. This correlation offers a promising approach to predict the rheological properties of bitumen in HMB mixtures by directly analyzing the chemical molecular weight distribution of the binders, thereby eliminating the need for an extraction process.
期刊介绍：
Materials (ISSN 1996-1944) is an open access journal of related scientific research and technology development. It publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Materials provides a forum for publishing papers which advance the in-depth understanding of the relationship between the structure, the properties or the functions of all kinds of materials. Chemical syntheses, chemical structures and mechanical, chemical, electronic, magnetic and optical properties and various applications will be considered.
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