N. A. Redmond, C. T. Hayes, R. F. Anderson, E. E. Black, R. L. Edwards, M. Q. Fleisher, X. Li, P. J. Lam, K. C. Mateos
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引用次数: 0
Abstract
An important role in the cycling of marine trace elements is scavenging, their adsorption and removal from the water column by sinking particles. Boundary scavenging occurs when areas of strong particle flux drive preferential removal of the trace metals at locations of enhanced scavenging. Due to its uniform production and quick burial via scavenging, 230Th is used to assess sedimentary mass fluxes; however, these calculations are potentially biased near regions where net lateral transport of dissolved 230Th violates the assumption that the flux of particulate 230Th to the seabed equals its rate of production in the water column. Here, we present a water column transect of dissolved 230Th along 152° W between Alaska and Tahiti (GEOTRACES GP15), where we examine 230Th profiles across multiple biogeochemical provinces and, novelly, the lateral transport of 230Th to distal East Pacific Rise hydrothermal plumes. We observed a strong relationship between the slope of dissolved 230Th concentration-depth profiles and suspended particle matter inventory in the upper-mid water column, reinforcing the view that biogenic particle mass flux sets the background 230Th distribution in open ocean settings. We find that, instead of the region of enhanced particle flux around the equator, hydrothermal plumes act as a regional boundary sink of 230Th. At 152° W, we found that the flux-to-production ratio, and thereby error in 230Th-normalized sediment flux, is between 0.80 and 1.50 for hydrothermal water, but the error is likely larger approaching the East Pacific Rise.
期刊介绍:
Global Biogeochemical Cycles (GBC) features research on regional to global biogeochemical interactions, as well as more local studies that demonstrate fundamental implications for biogeochemical processing at regional or global scales. Published papers draw on a wide array of methods and knowledge and extend in time from the deep geologic past to recent historical and potential future interactions. This broad scope includes studies that elucidate human activities as interactive components of biogeochemical cycles and physical Earth Systems including climate. Authors are required to make their work accessible to a broad interdisciplinary range of scientists.