Investigating pyrolytic carbon black in natural rubber compounds: rheological, mechanical and dynamic effects

IF 1.2 4区 化学 Q4 POLYMER SCIENCE
Gozde Kuru, Mert Goksuzoglu
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引用次数: 0

Abstract

The automotive industry, the highest consumer of carbon black, has established specific targets to integrate effective alternative materials such as pyrolytic carbon black. The purpose of this study is to explore the role of pyrolytic carbon black as a potential alternative filler in the rubber industry, focusing on its effects on processing, rheological, mechanical and dynamic properties. Four compounds were prepared using two pyrolytic carbon blacks with different surface areas and two conventional carbon blacks that are N330 and N550. The results indicated that the use of pyrolytic carbon black increases scorch and optimum cure times and decreases maximum and minimum torque. Tensile strength, elongation at break, modulus at 100% elongation and hardness of the compounds before and after aging were obtained and discussed. In addition, dynamic properties were obtained and it was observed that pyrolytic carbon black decreases tan delta. Pyrolytic carbon black also significantly decreases compound viscosity, enhancing processability. The thermal conductivity of compounds containing pyrolytic carbon blacks and conventional carbon blacks were also analyzed. Based on these findings, pyrolytic carbon black can be used as an alternative filler for specific applications.

Abstract Image

研究热解炭黑在天然橡胶化合物中的流变性、力学和动力学效应
汽车工业是炭黑的最大消费者,已经制定了具体的目标,以整合有效的替代材料,如热解炭黑。本研究的目的是探讨热解炭黑作为一种潜在的替代填料在橡胶工业中的作用,重点是它对橡胶的加工、流变、机械和动态性能的影响。用两种不同表面积的热解炭黑和两种常规炭黑N330和N550制备了四种化合物。结果表明,炭黑的使用增加了焦化时间和最佳固化时间,降低了最大和最小扭矩。得到并讨论了时效前后化合物的抗拉强度、断裂伸长率、100%伸长率模量和硬度。此外,还获得了炭黑的动力学性质,并观察到热解炭黑降低了tan δ。热解炭黑还显著降低了复合粘度,提高了加工性。分析了含热解炭黑和普通炭黑化合物的导热性。基于这些发现,热解炭黑可作为特定应用的替代填料。
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来源期刊
Journal of Rubber Research
Journal of Rubber Research 化学-高分子科学
自引率
15.40%
发文量
46
审稿时长
3 months
期刊介绍: The Journal of Rubber Research is devoted to both natural and synthetic rubbers, as well as to related disciplines. The scope of the journal encompasses all aspects of rubber from the core disciplines of biology, physics and chemistry, as well as economics. As a specialised field, rubber science includes within its niche a vast potential of innovative and value-added research areas yet to be explored. This peer reviewed publication focuses on the results of active experimental research and authoritative reviews on all aspects of rubber science. The Journal of Rubber Research welcomes research on: the upstream, including crop management, crop improvement and protection, and biotechnology; the midstream, including processing and effluent management; the downstream, including rubber engineering and product design, advanced rubber technology, latex science and technology, and chemistry and materials exploratory; economics, including the economics of rubber production, consumption, and market analysis. The Journal of Rubber Research serves to build a collective knowledge base while communicating information and validating the quality of research within the discipline, and bringing together work from experts in rubber science and related disciplines. Scientists in both academia and industry involved in researching and working with all aspects of rubber will find this journal to be both source of information and a gateway for their own publications.
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