Electrochemical reduction of spirocyclopentylmalonyl peroxide on smooth gold electrode in an aqueous medium

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-03-27 DOI:10.1007/s11172-025-4545-2

Ya. A. Barsegyan, M. D. Vedenyapina, V. A. Vil’, M. M. Kazakova

引用次数: 0

Abstract

Electrochemical reduction of cyclic diacyl peroxide (2,3-dioxaspiro[4.4]nonane-1,4-dione or spirocyclopentylmalonyl peroxide) was explored using a smooth platinum anode/smooth gold cathode pair in an aqueous medium. This peroxide during the electrolysis was selectively reduced to cyclopentane-1,1-dicarboxylic acid in 85% yield, while any decarboxylation products were not even observed. Taking into account the data acquired previously by cyclic voltammetry, the conclusion was drawn about proceeding the reduction of peroxide via two successive one-electron steps of electron transfer.

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水介质中光滑金电极上过氧化螺环戊基丙二醇的电化学还原

研究了在水介质中用光滑的铂阳极/光滑的金阴极对电化学还原环二酰基过氧化物（2,3-二氧嘧啶[4.4]壬烷-1,4-二酮或螺环戊基丙二醇过氧化物）。该过氧化物在电解过程中选择性地以85%的收率还原为环戊烷-1,1-二羧酸，而未观察到任何脱羧产物。考虑到以前用循环伏安法获得的数据，得出了通过两个连续的单电子转移步骤进行过氧化物还原的结论。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.