Rapid Explosive Synthesis of ZnO/Reduced Graphene Oxide Composites with Photocatalytic Degradation Properties under Simulated Sunlight

IF 0.9 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
S. S. Xu, Q. Q. Wang, C. W. Lai, J. X. Li
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Abstract

Zn(OH)2 and GO powders were used as the raw materials for an explosive reaction, resulting in the preparation of ZnO/reduced graphene oxide (rGO) composites. Results show that ZnO/rGO composites were obtained through the explosive reaction. GO was significantly stripped into nanosheets. GO was significantly stripped into nanosheets. ZnO had two distinct particle sizes: one falling in the submicron particle size of 100–500 nm and the other was being 5–10 nm. These ZnO nanoparticles were well supported on the rGO nanosheets. The photocatalytic degradation of methylene blue (MB) in an aqueous solution was studied. The findings demonstrate that the photocatalytic performance of the ZnO/rGO composites was greatly improved compared with that of the single-phase ZnO. Rapid degradation was achieved in a short time even at a high concentration of MB (60 mg/L). Under simulated sunlight irradiation, the ZnO/rGO composite prepared with a mole ratio of 1:8 of Zn(OH)2 and GO in the raw material can completely degrade MB within only 20 min.

Abstract Image

模拟阳光下快速爆炸合成具有光催化降解性能的ZnO/还原性氧化石墨烯复合材料
以Zn(OH)2和GO粉末为原料,进行爆炸反应,制备ZnO/还原氧化石墨烯(rGO)复合材料。结果表明,通过爆炸反应制备了ZnO/rGO复合材料。氧化石墨烯被剥离成纳米片。氧化石墨烯被剥离成纳米片。氧化锌有两种不同的粒径,一种是100-500 nm的亚微米粒径,另一种是5-10 nm的亚微米粒径。这些ZnO纳米粒子在氧化石墨烯纳米片上得到了良好的支撑。研究了水溶液中亚甲基蓝(MB)的光催化降解。研究结果表明,与单相ZnO相比,ZnO/rGO复合材料的光催化性能有了很大提高。即使在高浓度(60 mg/L)的条件下,也能在短时间内快速降解。在模拟阳光照射下,制备的ZnO/rGO复合材料在原料中Zn(OH)2与GO的摩尔比为1:8时,仅需20 min即可完全降解MB。
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来源期刊
CiteScore
1.40
自引率
22.20%
发文量
252
审稿时长
2-4 weeks
期刊介绍: Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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