Yang Xu , Fei Wang , Yuliang Zhang , Ting Shu , Wenchao Huang , Xinhao Yan , Yanhua Lei , Shifei Liu , Xiaobo Chen
{"title":"Robust photo/electrothermal synergistically all-weather anti/de-icing superhydrophobic composite coating based on modified graphene","authors":"Yang Xu , Fei Wang , Yuliang Zhang , Ting Shu , Wenchao Huang , Xinhao Yan , Yanhua Lei , Shifei Liu , Xiaobo Chen","doi":"10.1016/j.colsurfa.2025.136699","DOIUrl":null,"url":null,"abstract":"<div><div>Anti-icing/de-icing coatings on equipment surfaces are becoming an important protective measure against frost formation and buildup, especially when they are used in very harsh environments. Herein, perfluorodecyltriethoxysilane (FAS) has been grafted onto the surface of graphene (GPE) via hydrolysis in an alkaline condition. The FAS modified graphene (F-GPE) is hydrophobic and conductive. A photothermal and electrothermal superhydrophobic coating is obtained by mixing F-GPE into epoxy resin as a filler for anti/de-icing in cold condition. The coating has a fast electrothermal response speed and rapidly changes the surface temperature of the coating covered with ice and snow from −20 °C to 3.7 °C within 30 s under the safe voltage of 10–15 V. Even under frost conditions, the coating with ice layers could be restored through the synergy of light and electric-to-heat conversion. The ice layer is initially melt in about 90 s, and the ice-waterdrop mixture can be easily removed on the superhydrophobic F-GPE coating. In addition, the coating shows superior mechanical strength. These remarkable properties make it valuable for application and more possibilities in the all-weather anti-icing and de-icing field.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"716 ","pages":"Article 136699"},"PeriodicalIF":4.9000,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927775725006016","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Anti-icing/de-icing coatings on equipment surfaces are becoming an important protective measure against frost formation and buildup, especially when they are used in very harsh environments. Herein, perfluorodecyltriethoxysilane (FAS) has been grafted onto the surface of graphene (GPE) via hydrolysis in an alkaline condition. The FAS modified graphene (F-GPE) is hydrophobic and conductive. A photothermal and electrothermal superhydrophobic coating is obtained by mixing F-GPE into epoxy resin as a filler for anti/de-icing in cold condition. The coating has a fast electrothermal response speed and rapidly changes the surface temperature of the coating covered with ice and snow from −20 °C to 3.7 °C within 30 s under the safe voltage of 10–15 V. Even under frost conditions, the coating with ice layers could be restored through the synergy of light and electric-to-heat conversion. The ice layer is initially melt in about 90 s, and the ice-waterdrop mixture can be easily removed on the superhydrophobic F-GPE coating. In addition, the coating shows superior mechanical strength. These remarkable properties make it valuable for application and more possibilities in the all-weather anti-icing and de-icing field.
期刊介绍:
Colloids and Surfaces A: Physicochemical and Engineering Aspects is an international journal devoted to the science underlying applications of colloids and interfacial phenomena.
The journal aims at publishing high quality research papers featuring new materials or new insights into the role of colloid and interface science in (for example) food, energy, minerals processing, pharmaceuticals or the environment.