Synthesis of biodiesel and prepared its blend: An ecofriendly, clean, alternative, and sustainable energy source

Madhuri A. Balpande , Manish M. Katiya , Madhukar G. Dhonde , Jayant M. Gajbhiye
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Abstract

A base catalyzed the transesterification reaction, resulting in a 98 % yield during biodiesel (fatty acid methyl ester - FAME) synthesis. The optimization reaction protocol requires maximum agitation of 600 rpm at room temperature for 20min with a 10mol% KOH as a base catalyst and 1:8 ratios of sunflower oil and methanol to complete the reaction. This study examines the viability of using vegetable oil through transesterification to produce biodiesel on a commercial scale, with the goal of serving as a fuel substitute for diesel engines. We explored well-established spectroscopic techniques, including Infra-Red, 1H, 13C Nuclear Magnetic Resonance, Gas Chromatography Mass Spectra, and High-Resolution Mass Spectra, to investigate the synthesized FAME in accordance with the ASTM specification. The novelty of the current study outlines the significance of synthesizing FAME through catalytic transesterification, examines its physicochemical parameters, and green chemistry matrices have shown that biodiesel is a beneficial fuel, which led to less reaction waste, better environmental compatibility, and long-term use of the current protocol. In addition to exploring biodiesel's fuel applications; we are also looking into its possible uses as a biodetergent for other purposes and a biolubricant for diesel engines. The study highlights the simple, efficient development of current biodiesel, with its sustainability, and its potential contribution to renewable energy goals. It also explores the environmental impact of transitioning to biobased alternatives and its potential applications in industries like cosmetics and automobiles. Therefore, this investigation aims to explore and combine the unique advantages associated with varying ratios of additives in FAME, with the goal of replacing as much diesel as possible. We created and experimented with blends including 10, 20, and 30 % ethanol or iso-octane in FAME; nevertheless, the blend containing 30 % ethanol works better as a diesel substitute.

Abstract Image

生物柴油的合成及其混合物:一种环保、清洁、可替代和可持续的能源
一种碱催化酯交换反应,合成生物柴油(脂肪酸甲酯- FAME)的产率达到98%。优化的反应方案要求以10mol% KOH为基础催化剂,葵花籽油和甲醇的比例为1:8,室温下最大搅拌转速为600 rpm,搅拌20min。本研究考察了利用植物油通过酯交换法在商业规模上生产生物柴油的可行性,其目标是作为柴油发动机的燃料替代品。我们探索了成熟的光谱技术,包括红外、1H、13C核磁共振、气相色谱质谱和高分辨率质谱,以研究合成的FAME符合ASTM规范。本研究的新颖性概述了通过催化酯交换合成FAME的意义,考察了其物理化学参数,绿色化学矩阵表明生物柴油是一种有益的燃料,导致较少的反应浪费,更好的环境相容性,并长期使用当前的方案。除了探索生物柴油的燃料应用;我们也在研究它作为其他用途的生物洗涤剂和柴油发动机的生物润滑剂的可能用途。该研究强调了当前生物柴油的简单、高效的发展,以及它的可持续性,以及它对可再生能源目标的潜在贡献。它还探讨了向生物基替代品过渡对环境的影响及其在化妆品和汽车等行业的潜在应用。因此,本研究旨在探索和结合FAME中不同比例添加剂的独特优势,以尽可能多地替代柴油。我们在FAME中创建并试验了包括10%,20%和30%乙醇或异辛烷的混合物;然而,含有30%乙醇的混合物作为柴油替代品效果更好。
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