Correlation between the size of the inter-platelet cation in the montmorillonite and the influence of MMT on the performance of silicone pressure-sensitive adhesives
Adrian Krzysztof Antosik , Karolina Mozelewska , Agata Kraśkiewicz , Marlena Musik , Piotr Miądlicki , Marcin Bartkowiak
{"title":"Correlation between the size of the inter-platelet cation in the montmorillonite and the influence of MMT on the performance of silicone pressure-sensitive adhesives","authors":"Adrian Krzysztof Antosik , Karolina Mozelewska , Agata Kraśkiewicz , Marlena Musik , Piotr Miądlicki , Marcin Bartkowiak","doi":"10.1016/j.ijadhadh.2025.104021","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, various types of montmorillonite (H+, Na+, Ca+) were employed as additives for the physical modification of commercially available silicone pressure-sensitive adhesives (Si-PSA). Additionally, a modification of sodium montmorillonite was carried out to obtain the MMT-Al variant. Prior to adding MMTs to the Si-PSA composition, analyses of MMTs were performed using XRD technique. New self-adhesive materials were created by incorporating the prepared fillers into a polymer matrix based on Si-PSA. The new tapes exhibited retained or slightly reduced values of key performance parameters, such as adhesion (10–14 N/25 mm), cohesion (>72h), and shrikage (<0.5 %). Furthermore, tapes with the addition of MMTs showed excellent thermal resistance, reaching application temperatures up to 225 °C, surpassing the measurement limits of the available research apparatus.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104021"},"PeriodicalIF":3.2000,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Adhesion and Adhesives","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0143749625000880","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
In this study, various types of montmorillonite (H+, Na+, Ca+) were employed as additives for the physical modification of commercially available silicone pressure-sensitive adhesives (Si-PSA). Additionally, a modification of sodium montmorillonite was carried out to obtain the MMT-Al variant. Prior to adding MMTs to the Si-PSA composition, analyses of MMTs were performed using XRD technique. New self-adhesive materials were created by incorporating the prepared fillers into a polymer matrix based on Si-PSA. The new tapes exhibited retained or slightly reduced values of key performance parameters, such as adhesion (10–14 N/25 mm), cohesion (>72h), and shrikage (<0.5 %). Furthermore, tapes with the addition of MMTs showed excellent thermal resistance, reaching application temperatures up to 225 °C, surpassing the measurement limits of the available research apparatus.
期刊介绍:
The International Journal of Adhesion and Adhesives draws together the many aspects of the science and technology of adhesive materials, from fundamental research and development work to industrial applications. Subject areas covered include: interfacial interactions, surface chemistry, methods of testing, accumulation of test data on physical and mechanical properties, environmental effects, new adhesive materials, sealants, design of bonded joints, and manufacturing technology.