Construction of high-performance aqueous zinc-ion batteries by guest pre-intercalation MnO2-based cathodes

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science Pub Date : 2025-03-25 DOI:10.1016/j.cis.2025.103499

Lu-Lu Zhao , Jun-Wei Yin , Bing-Chen Liu , Peng-Fei Wang , Zong-Lin Liu , Ying Xie , Jie Shu , Qian-Yu Zhang , Ting-Feng Yi

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Abstract

In recent years, aqueous zinc ion batteries (AZIBs) with the benefits of high safety, low cost, high capacity and environmental protection, have broad development prospects in the area of massive energy storage. Among them, MnO₂ materials are seen to be the most prospective cathode materials because of their low manufacturing costs, high operating voltage, and multi-valence state. Nevertheless, issues with low intrinsic conductivity, quick structural collapse and poor stability of MnO₂ cathode materials during the charge/discharge process severely impede the development of AZIBs. Numerous investigations have demonstrated that the guest pre-intercalation MnO₂ cathode structures can effectively alleviate the above problems and improve their electrochemical performance. Thus, this review summarizes the research progress of the guest pre-intercalation strategy applied to different Mn-based oxide cathode materials, focusing on α-MnO₂, β-MnO₂, ε-MnO₂, δ-MnO₂, and γ-MnO₂. Meanwhile, the mechanism of performance improvement and electronic structure alteration of guest pre-intercalation in MnO₂ cathode materials with different crystal structures are analyzed in detail. Finally, the challenges faced by this strategy and its development are summarized, and the future development direction of Mn-based cathode materials for high-performance AZIBs is prospected. The review describes the guest pre-intercalation strategy that promotes the commercialization and practical application of AZIBs, providing strong support for the development of renewable energy storage.

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来源期刊

Advances in Colloid and Interface Science 化学-物理化学

CiteScore

28.50

自引率

2.60%

发文量

175

审稿时长

31 days

期刊介绍： "Advances in Colloid and Interface Science" is an international journal that focuses on experimental and theoretical developments in interfacial and colloidal phenomena. The journal covers a wide range of disciplines including biology, chemistry, physics, and technology. The journal accepts review articles on any topic within the scope of colloid and interface science. These articles should provide an in-depth analysis of the subject matter, offering a critical review of the current state of the field. The author's informed opinion on the topic should also be included. The manuscript should compare and contrast ideas found in the reviewed literature and address the limitations of these ideas. Typically, the articles published in this journal are written by recognized experts in the field.