Synchronous Hetero-Interface and Vacancy Engineering for Construction of Pitaya-Like CoSe1-x/C@NC@ZnSe Nanosphere Toward Ultrastable Sodium-Ion Half/Full Batteries

IF 24.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Wenpei Kang, Mengjia Han, Mang Niu, Yazhan Liang, Ying Hu, Xiaoyu Fan, Xuguang An, Baojuan Xi, Daofeng Sun, Shenglin Xiong
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引用次数: 0

Abstract

Transition metal selenides have attracted extensive attention as promising anode materials for sodium-ion batteries (SIBs) due to their fascinating physical chemistry characteristics. However, its cycling performance especially at high currents, is still unsatisfactory owing to the intrinsic limited conductivity. Herein, N-doped carbon shell coated and ZnSe bonded Se-vacancy enriched CoSe1-x (CoSe1-x/C@NC@ZnSe, CZSCV) nanospheres with abundant hetero-interfaces are designed through an in situ Se transfer strategy. Owing to the ingenious structure, as an anode material in SIBs, CZSCV demonstrates superior cycling stability (363.5 mAh g−1 at 10 A g−1 after 1000 cycles) and high-rate sodium storage capability (193.9 mAh g−1 at 20 A g−1 after 5000 cycles). Meanwhile, in the CZSCV//Na3V2(PO4)3@C full cell, it also delivers a stable capacity of 201.4 mAh g−1 at 1.0 A g−1 and provides a high energy density of 397.4 Wh kg−1 with a power density of 231.6 W kg−1. Based on the kinetics analysis and the density functional theory calculation, the hetero-interfaces and enriched Se-vacancies can synergistically accelerate the Na+/electron transfer, owing to the charge redistribution, the decreased diffusion barrier of Na+ and increased pseudo-capacitive capacity contribution. As a result, excellent high-rate anode material can be achieved for the SIBs.

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来源期刊
Advanced Energy Materials
Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
41.90
自引率
4.00%
发文量
889
审稿时长
1.4 months
期刊介绍: Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
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