Abundant Transition Metal Based Photocatalysts for Red Light Driven Photocatalysis.

Abstract

Photocatalysis emerges as an efficient and versatile tool for the preparation of organic compounds via development of new methodologies and new photosensitizers. Mostly UV and blue light irradiation are used for such reactions. Red light is low energy light, it is less harmful and has more penetration depth. Hence red light driven photocatalysis would be more suitable for preparing value added products. Red absorbing photosensitizers are mostly based on rare and expensive metals. In this review, we describe the recent developments on Earth-abundant transition metal-based photosensitizers (W(0), Mo(0), Cr(0), Fe(III), Cu(I), Zn(II)) and their applications in red light driven photocatalysis. Photocatalysis using both electron transfer and energy transfer processes are discussed. Three different red light induced reactions such as direct monophotonic excitation, sensitized triplet-triplet annihilation upconversion (sTTA-UC) and dual red light photocatalysis are presented. Various organic transformations such as reductive dehalogenation and detosylation, reduction of diazonium salts, C-C coupling via C-H activation, oxidation of aryl boronic acids to phenols, polymerization reactions, cross dehydrogenative couplings, α-cyanation of tertiary amines, Barton decarboxylation have been carried out using abundant photosensitizers and red light.