Construction of carboxylated multi-walled carbon nanotube/copper oxide/nano silver modified graphite felt electrode and its adsorption mechanism for UO22+

IF 1.5 3区 化学 Q3 CHEMISTRY, ANALYTICAL
Mengshi Hu, Qian Li, Guangyue Li, Tingting Liu, Xiaowei Zhou, Jing Sun, Zhao Cui, Ting Li
{"title":"Construction of carboxylated multi-walled carbon nanotube/copper oxide/nano silver modified graphite felt electrode and its adsorption mechanism for UO22+","authors":"Mengshi Hu,&nbsp;Qian Li,&nbsp;Guangyue Li,&nbsp;Tingting Liu,&nbsp;Xiaowei Zhou,&nbsp;Jing Sun,&nbsp;Zhao Cui,&nbsp;Ting Li","doi":"10.1007/s10967-025-10001-9","DOIUrl":null,"url":null,"abstract":"<div><p>Uranium-containing wastewater from the nuclear fuel cycle poses severe hazards to human health and the environment. In this study, a carboxylated multi-walled carbon nanotube/copper oxide/nano silver modified graphite felt electrode (MCA) material was designed, exhibiting electrosorption performance with electrical double layer and pseudocapacitance characteristics. Electrosorption processes proved the ability to adsorb U(VI). MCA-2 had the highest removal rate (93.31%) due to superior conductivity, stability, and capacitance characteristics. A high adsorption capacity of 361 mg/g was reached in a 200 mg/L U(VI) solution. MCA achieves good cycling stability and high selectivity, making it a potential electrode material for radioactive wastewater treatment.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"334 3","pages":"2501 - 2516"},"PeriodicalIF":1.5000,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Radioanalytical and Nuclear Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10967-025-10001-9","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Uranium-containing wastewater from the nuclear fuel cycle poses severe hazards to human health and the environment. In this study, a carboxylated multi-walled carbon nanotube/copper oxide/nano silver modified graphite felt electrode (MCA) material was designed, exhibiting electrosorption performance with electrical double layer and pseudocapacitance characteristics. Electrosorption processes proved the ability to adsorb U(VI). MCA-2 had the highest removal rate (93.31%) due to superior conductivity, stability, and capacitance characteristics. A high adsorption capacity of 361 mg/g was reached in a 200 mg/L U(VI) solution. MCA achieves good cycling stability and high selectivity, making it a potential electrode material for radioactive wastewater treatment.

羧化多壁碳纳米管/氧化铜/纳米银改性石墨毡电极的构建及其对UO22+的吸附机理
核燃料循环产生的含铀废水对人类健康和环境构成严重危害。本研究设计了一种羧化多壁碳纳米管/氧化铜/纳米银修饰石墨毡电极(MCA)材料,该材料具有双电层电吸附性能和赝电容特性。电吸附过程证明了吸附U(VI)的能力。MCA-2具有优异的电导率、稳定性和电容特性,去除率最高(93.31%)。在200 mg/L的U(VI)溶液中,吸附量达到361 mg/g。MCA具有良好的循环稳定性和高选择性,是一种潜在的放射性废水处理电极材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
2.80
自引率
18.80%
发文量
504
审稿时长
2.2 months
期刊介绍: An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信