{"title":"Uniform-sized (K, Na)NbO3 nanocrystallines as potential photocatalytic materials","authors":"Yanqing Liu, Liangliang Liu, Zhaoping Hou","doi":"10.1016/j.matlet.2025.138449","DOIUrl":null,"url":null,"abstract":"<div><div>(K, Na)NbO<sub>3</sub> materials with piezoelectric effect are considered to be very competitive compounds in the field of optoelectronics. The low crystallinity and stability of the raw materials have limited the development of the (K, Na)NbO<sub>3</sub> materials. In this work, a new strategy combining solid phase reaction and molten salt methods has been designed to synthesize (K, Na)NbO<sub>3</sub> powder. Uniform-sized (K, Na)NbO<sub>3</sub> nanocrystallines were obtained in the K<sub>0.5</sub>Na<sub>0.5</sub>NbO<sub>3</sub>-KCl system at 900 °C. The electric properties of the (K, Na)NbO<sub>3</sub> ceramics suggested that the chemical composition of the nanocrystalline closed to the stoichiometric ratio of K<sub>0.5</sub>Na<sub>0.5</sub>NbO<sub>3</sub>. It was found that the degradation rate of (K, Na)NbO<sub>3</sub> nanocrystallines on methylene blue (MB) solution reached 68 % under visible light irradiation. This study shows that (K, Na)NbO<sub>3</sub> has great potential in the environmental remediation of polluted water.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"390 ","pages":"Article 138449"},"PeriodicalIF":2.7000,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167577X25004781","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
(K, Na)NbO3 materials with piezoelectric effect are considered to be very competitive compounds in the field of optoelectronics. The low crystallinity and stability of the raw materials have limited the development of the (K, Na)NbO3 materials. In this work, a new strategy combining solid phase reaction and molten salt methods has been designed to synthesize (K, Na)NbO3 powder. Uniform-sized (K, Na)NbO3 nanocrystallines were obtained in the K0.5Na0.5NbO3-KCl system at 900 °C. The electric properties of the (K, Na)NbO3 ceramics suggested that the chemical composition of the nanocrystalline closed to the stoichiometric ratio of K0.5Na0.5NbO3. It was found that the degradation rate of (K, Na)NbO3 nanocrystallines on methylene blue (MB) solution reached 68 % under visible light irradiation. This study shows that (K, Na)NbO3 has great potential in the environmental remediation of polluted water.
期刊介绍:
Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials.
Contributions include, but are not limited to, a variety of topics such as:
• Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors
• Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart
• Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction
• Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots.
• Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing.
• Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic
• Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive