Advances in the selective functionalization of B(3,6)-H of o-carboranes.

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-03-25 DOI:10.1039/d4ob01778a

Ji Wu, Ke Cao

引用次数: 0

Abstract

This review summarizes the methodologies for the selective functionalization of the B(3,6) vertices of o-carboranes, including the deboration-capitation reaction, the coupling reaction of B-X (X = I, Br) bonds, reactions of 1,3-dehydro-o-carborane and [3-N₂-o-C₂B₁₀H₁₁][BF₄] as well as transition-metal-catalyzed B-H activation. These works offer a versatile toolbox for synthesizing B(3,6)-substituted o-carborane derivatives and will promote their applications in material science, pharmaceutical chemistry, and related disciplines.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.