Bimetallic SERS platform with femtomolar sensitivity for in situ monitoring of catalytic reactions

IF 4.3 2区化学 Q1 SPECTROSCOPY

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Pub Date : 2025-03-22 DOI:10.1016/j.saa.2025.126092

Yuqi Wan , Jingkun Li , Guoyong Jiang , Fuwei Pi

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引用次数: 0

Abstract

We developed a gold-silver bimetallic surface-enhanced Raman scattering (SERS) chip (AuNPs@AuAg NSs island array chip) that combines excellent SERS enhancement with in situ catalytic properties. This platform exhibits superior plasmonic catalytic capabilities, enabling rapid in situ monitoring of redox reactions without the need for chemical reductants. Additionally, under simulated sunlight, the chip achieved effective degradation of methylene blue (MB) molecules, with a removal rate of 95.65 %, demonstrating its potential for environmental safety applications. The chip’s uniform and dense SERS hotspots allow for the detection of pollutants at extremely low concentrations (as low as 10⁻¹⁵ M), offering a powerful tool for trace-level detection of hazardous substances. This work highlights the potential of such nanostructures for in situ monitoring of catalytic reactions and pollutant degradation, as well as for rapid, non-destructive, and high-throughput detection of ultra-low concentrations of analytes.

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来源期刊

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 物理-光谱学

CiteScore

8.40

自引率

11.40%

发文量

1364

审稿时长

40 days

期刊介绍： Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (SAA) is an interdisciplinary journal which spans from basic to applied aspects of optical spectroscopy in chemistry, medicine, biology, and materials science. The journal publishes original scientific papers that feature high-quality spectroscopic data and analysis. From the broad range of optical spectroscopies, the emphasis is on electronic, vibrational or rotational spectra of molecules, rather than on spectroscopy based on magnetic moments. Criteria for publication in SAA are novelty, uniqueness, and outstanding quality. Routine applications of spectroscopic techniques and computational methods are not appropriate. Topics of particular interest of Spectrochimica Acta Part A include, but are not limited to: Spectroscopy and dynamics of bioanalytical, biomedical, environmental, and atmospheric sciences, Novel experimental techniques or instrumentation for molecular spectroscopy, Novel theoretical and computational methods, Novel applications in photochemistry and photobiology, Novel interpretational approaches as well as advances in data analysis based on electronic or vibrational spectroscopy.