Pilot-Scale Photoreforming of Hydrolyzed Polylactic Acid Waste to High-Value Chemicals and H2 via Atomic Ru Integration

IF 24.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Feng Liu, Chunyang Zhang, Kejian Lu, Xueli Yan, Yi Wang, Dengwei Jing, Liejin Guo, Maochang Liu
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引用次数: 0

Abstract

Photoreforming of polylactic acid (PLA) waste into valuable chemicals offers a promising approach for environmental protection and waste valorization, yet faces challenges of low yields and harsh conditions. Herein, a Cd0.5Zn0.5S nanotwin catalyst decorated with Ru single atoms and clusters is reported, enabling selective photoreforming of PLA into pyruvic acid (PA) and H2. It is demonstrated that Ru single atoms favor PA formation via hydroxyl dissociation, while the further incorporation of Ru clusters serve as active sites for H2 production. This synergistic effect significantly enhances photocatalytic performance, achieving 96.8% PA selectivity and efficient H2 production with a record-breaking apparent quantum efficiency of 83.7% at 400 nm. This approach is scalable for outdoor processes, utilizing direct 1 m2 sunlight irradiation to deliver ≈1191 mL h−1 of H2 and 47.27 mmol h−1 of PA from PLA waste, paving a viable pathway for large-scale simultaneous production of high-value chemicals and H2.

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来源期刊
Advanced Energy Materials
Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
41.90
自引率
4.00%
发文量
889
审稿时长
1.4 months
期刊介绍: Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
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