{"title":"Structural Modulation in Viologen-Based Ionic Porous Organic Polymers for Catalytic Non-Redox CO2 Fixation","authors":"Tapolabdha Lodh, G. Shreeraj, Abhijit Patra","doi":"10.1002/macp.202400373","DOIUrl":null,"url":null,"abstract":"<p>The rational design of metal-free, porous, and heterogeneous catalysts with large specific surface areas for efficient CO<sub>2</sub> capture and utilization has remained a significant challenge. In this study, two structurally distinct viologen-based novel ionic porous organic polymers (iPOPs) featuring a triazine core are developed, employing different polymerization methods to modulate their porosity and catalytic properties. The alkyne-linked SC-iPOP, synthesized through Sonogashira polycondensation, exhibits high porosity (specific BET surface area: 616 ± 9 m<sup>2</sup> g<sup>−1</sup>) over BHC-iPOP with secondary amine linkages fabricated by Buchwald-Hartwig polymerization. SC-iPOP demonstrates superior catalytic efficiency in the metal-free cycloaddition of CO<sub>2</sub> with epoxides to form cyclic organic carbonates under atmospheric pressure and solvent-free conditions, with excellent recyclability. This enhanced catalytic performance, compared to BHC-iPOP, is attributed to the high porosity of SC-iPOP and the presence of abundant CO<sub>2</sub>-philic ionic active sites. The current study emphasizes the role of structural modifications in designing efficient porous catalysts for metal-free CO<sub>2</sub> fixation.</p>","PeriodicalId":18054,"journal":{"name":"Macromolecular Chemistry and Physics","volume":"226 6","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Chemistry and Physics","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/macp.202400373","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
The rational design of metal-free, porous, and heterogeneous catalysts with large specific surface areas for efficient CO2 capture and utilization has remained a significant challenge. In this study, two structurally distinct viologen-based novel ionic porous organic polymers (iPOPs) featuring a triazine core are developed, employing different polymerization methods to modulate their porosity and catalytic properties. The alkyne-linked SC-iPOP, synthesized through Sonogashira polycondensation, exhibits high porosity (specific BET surface area: 616 ± 9 m2 g−1) over BHC-iPOP with secondary amine linkages fabricated by Buchwald-Hartwig polymerization. SC-iPOP demonstrates superior catalytic efficiency in the metal-free cycloaddition of CO2 with epoxides to form cyclic organic carbonates under atmospheric pressure and solvent-free conditions, with excellent recyclability. This enhanced catalytic performance, compared to BHC-iPOP, is attributed to the high porosity of SC-iPOP and the presence of abundant CO2-philic ionic active sites. The current study emphasizes the role of structural modifications in designing efficient porous catalysts for metal-free CO2 fixation.
期刊介绍:
Macromolecular Chemistry and Physics publishes in all areas of polymer science - from chemistry, physical chemistry, and physics of polymers to polymers in materials science. Beside an attractive mixture of high-quality Full Papers, Trends, and Highlights, the journal offers a unique article type dedicated to young scientists – Talent.