Sebastian Mack, Katrin Krieg, Christopher Teßmann, Daniel Ourinson, Jana-Isabelle Polzin, Andreas Wolf
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引用次数: 0
Abstract
Front side recombination in tunnel oxide passivated contact solar cells is frequently described by the recombination parameters j0e for the passivated and j0e,met for the metallized front region. The combination of Al-free metallization pastes and current-assisted contact formation has shown significant reduction of j0e,met. Such new metallization approaches enable shallower doping profiles and higher sheet resistances Rsheet, which in turn also reduce j0e. In this study, we provide insight into how to reduce the overall front side recombination, by tailoring the boron dopant profile from atmospheric pressure BBr3 diffusion processes. The limitation of the dopant dose in the profile leads to a higher Rsheet of the resulting profile. The newly developed homogeneous boron emitter features j0e = 14 fA cm−2 at a Rsheet = 161 Ω sq−1, a 62% decrease from the initial value, and an even lower j0e = 8 fA cm−2 is determined for an emitter with 330 Ω sq−1. An increased contact resistivity on the front side still poses a challenge for Ag front side pastes despite the use of current-assisted contact formation. Application of an alternative AgAl paste in industrial-type fabricated TOPCon solar cells results in a maximum conversion efficiency of 24.5%.
Solar RRLPhysics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍:
Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.