{"title":"Role of Reducible and Mobile Oxygens in Methane Partial Oxidation Within a Post-Plasma Catalytic System","authors":"Yu-Chuan Lin, You-Cheng Lin, Kun-Jie Huang, Rui-Ping Yeh, Franklin Chau-Nan Hong, Yih-Ming Shyu","doi":"10.1002/slct.202405886","DOIUrl":null,"url":null,"abstract":"<p>This study examines methane oxidation in a post-plasma catalysis (PPC) system. Using dielectric barrier discharge plasma with metal oxide-supported catalysts (Cu/Al, Ni/Al, Fe/Al, and NaW/Al), the effects of reactant feed type, composition, and catalyst oxygen species were evaluated for optimizing plasma-catalytic performance. Key findings indicate that extended O<sub>2</sub> contact time, reduced CH<sub>4</sub> contact time, water addition to the feed, and the use of mobile oxygen-enriched catalyst, that is NaW/Al, positively influence the extent of partial oxidation. Notably, the mobile oxygen in NaW/Al plays a role in improving the yields of partial oxidation products (CH<sub>3</sub>OH, HCOH, and HCOOH) and can be replenished through calcination within the PPC system.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 12","pages":""},"PeriodicalIF":1.9000,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistrySelect","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/slct.202405886","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
This study examines methane oxidation in a post-plasma catalysis (PPC) system. Using dielectric barrier discharge plasma with metal oxide-supported catalysts (Cu/Al, Ni/Al, Fe/Al, and NaW/Al), the effects of reactant feed type, composition, and catalyst oxygen species were evaluated for optimizing plasma-catalytic performance. Key findings indicate that extended O2 contact time, reduced CH4 contact time, water addition to the feed, and the use of mobile oxygen-enriched catalyst, that is NaW/Al, positively influence the extent of partial oxidation. Notably, the mobile oxygen in NaW/Al plays a role in improving the yields of partial oxidation products (CH3OH, HCOH, and HCOOH) and can be replenished through calcination within the PPC system.
期刊介绍：
ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
