Richard Rudolf, Andrej Todorovski, Vera Lederer, Nicolas I. Neuman, Hartmut Schubert, Biprajit Sarkar
{"title":"Inside Back Cover: An Anionic Mesoionic Carbene (anMIC) and its Transformation to Metallo MIC-Boranes: Synthesis and Properties","authors":"Richard Rudolf, Andrej Todorovski, Vera Lederer, Nicolas I. Neuman, Hartmut Schubert, Biprajit Sarkar","doi":"10.1002/ange.202504464","DOIUrl":null,"url":null,"abstract":"<p>Mirror, mirror on the wall, who is the smartest of them all? The combination of B(C<sub>6</sub>F<sub>5</sub>)3 with a 1,2,3-triazole unleashed remarkable new possibilities, as reported by Biprajit Sarkar et al. in their Research Article (e202422702). The mirror images show the three different compounds to which the starting material can convert to: a strongly donating anionic mesoionic carbene ligand (MIC), metallo-MIC-borane adducts and bis-borane adducts of MICs. This simple yet astonishing concept provides a platform for new, intriguing MIC-based compounds with high potential in catalysis.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 13","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202504464","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202504464","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
Mirror, mirror on the wall, who is the smartest of them all? The combination of B(C6F5)3 with a 1,2,3-triazole unleashed remarkable new possibilities, as reported by Biprajit Sarkar et al. in their Research Article (e202422702). The mirror images show the three different compounds to which the starting material can convert to: a strongly donating anionic mesoionic carbene ligand (MIC), metallo-MIC-borane adducts and bis-borane adducts of MICs. This simple yet astonishing concept provides a platform for new, intriguing MIC-based compounds with high potential in catalysis.
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