An insight into biomass-derived low-cost biochar supported FeNi3/NiFe2O4 catalyst: Effect of hydrothermal treatment and carbothermal reduction temperature

Abstract

To address the issue of tar removal during biomass gasification, a biochar supported FeNi₃/NiFe₂O₄ catalyst was prepared using sawdust as the precursor at a temperatures range of 600–800 °C. The influence of carbothermal reduction temperature on the physicochemical properties of the catalysts was explored. Following hydrothermal treatment, the metal particles were embedded within the hydrochars. Subsequently, the metal particles further etched the carbon support and underwent vapor phase deposition of volatile components during the carbothermal reduction process, forming a composite structure of porous carbon inside the external carbon nanofibers. The carbothermal reduction temperature of 700 °C is regarded as the optimum, leading to the formation of highly dispersed NiFe₂O₄ active phase which exhibited a significant abundance of oxygen vacancies within the catalyst. Additionally, catalytic cracking of tar was performed in both in-situ and ex-situ conditions at 600 °C to examine the overall catalytic performance of the catalysts. The catalysts HT700Fe-Ni@Char prepared at 700 °C exhibited an ex-situ tar conversion efficiency of 96.02 %, which was maintained at 86.32 % even after five cycles. The preservation of the NiFe₂O₄ active phase at elevated temperatures and the hindrance effect of carbon nanofibers on the accumulation of bulky coke were crucial factors for ensuring the sustainability of catalyst performance.