Unraveling the fate of phosphorus in alluvial aquifers of the middle-lower Yellow River: Coupled natural and anthropogenic impacts

Abstract

In recent years, groundwater phosphorus (P) contamination has received increasing attention, yet most studies focus solely on either anthropogenic or geogenic influences. This research addressed the combined effects of human activities and natural processes on P enrichment in the middle-lower Yellow River basin, where dissolved inorganic phosphorus (DIP) concentrations reached 0.59 mg/L. Hydrogeochemical analysis, along with multiple statistical methods and the Redfield ratio, revealed that geogenic processes were the dominant drivers of groundwater P enrichment, accounting for 77.5 % of the samples, while anthropogenic activities, particularly intensive agriculture, densely residential area and industrial development, contributed to P inputs in 22.5 % of the samples. Further analysis using dual isotopes (δ¹³C-DIC and δ⁵⁶Fe) demonstrated that OP mineralization was the dominant geogenic P enrichment process, with the reductive dissolution of P-rich iron minerals serving as a secondary contributor. A comparative analysis between the middle-lower Yellow River basin and the central Yangtze River basin highlighted that the abundance of natural P-containing carriers and the closed or open nature of the groundwater environment jointly determined the extent of geogenic and anthropogenic P enrichment. This study provides valuable insights into the coupled impacts of natural and anthropogenic factors, enhancing our understanding of groundwater P dynamics.