Youyi Li , Yuhan Liu , Kun-Peng Wang , Zhenyu Xiao , Qi Zhang , Lei Wang , Volodymyr Turkevych
{"title":"Epitaxial growth of the (101) plane: High stability and dendrite-free Zn anode achieved by “one stone, two birds” strategy","authors":"Youyi Li , Yuhan Liu , Kun-Peng Wang , Zhenyu Xiao , Qi Zhang , Lei Wang , Volodymyr Turkevych","doi":"10.1016/j.ensm.2025.104204","DOIUrl":null,"url":null,"abstract":"<div><div>The performance of zinc ion batteries (ZIBs) is significantly constrained by dendrite growth and side reactions on the Zn anode. While epitaxial growth is an efficient strategy to stabilize the Zn anode by directing crystal alignment, the direct contact between the exposed crystal and electrolyte results in severe parasitic reactions. Here, we present a selective etching strategy on Zn anodes (denoted as ACE-Zn) that preferentially exposes the (101) plane, which features strong epitaxial growth characteristics to facilitate stably dense stacking of Zn atoms. Notably, the (101) plane also promotes the formation of a ZnS solid electrolyte interphase (SEI). This ZnS SEI exhibits high hydrophilicity and an ultrathin structure, contributing to exceptional ion transfer rate and isolating the Zn anode from water-related side reactions. As a result, ACE-Zn symmetric cells achieve an impressive cycle life of 4920 h at 0.5 mAh cm<sup>−2</sup> and 0.5 mA cm<sup>−2</sup>, along with a high average Coulombic efficiency (CE) of 99.93 % over 3500 cycles. Furthermore, V-EG//ACE-Zn button-cells demonstrate prolonged cycle life of 7600 cycles at 10 A g<sup>−1</sup>. We believe this “one stone, two birds” strategy will provide new insights into texturing preferential planes and constructing SEI to stabilize Zn anodes.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104204"},"PeriodicalIF":18.9000,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy Storage Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2405829725002041","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The performance of zinc ion batteries (ZIBs) is significantly constrained by dendrite growth and side reactions on the Zn anode. While epitaxial growth is an efficient strategy to stabilize the Zn anode by directing crystal alignment, the direct contact between the exposed crystal and electrolyte results in severe parasitic reactions. Here, we present a selective etching strategy on Zn anodes (denoted as ACE-Zn) that preferentially exposes the (101) plane, which features strong epitaxial growth characteristics to facilitate stably dense stacking of Zn atoms. Notably, the (101) plane also promotes the formation of a ZnS solid electrolyte interphase (SEI). This ZnS SEI exhibits high hydrophilicity and an ultrathin structure, contributing to exceptional ion transfer rate and isolating the Zn anode from water-related side reactions. As a result, ACE-Zn symmetric cells achieve an impressive cycle life of 4920 h at 0.5 mAh cm−2 and 0.5 mA cm−2, along with a high average Coulombic efficiency (CE) of 99.93 % over 3500 cycles. Furthermore, V-EG//ACE-Zn button-cells demonstrate prolonged cycle life of 7600 cycles at 10 A g−1. We believe this “one stone, two birds” strategy will provide new insights into texturing preferential planes and constructing SEI to stabilize Zn anodes.
锌离子电池的性能主要受枝晶生长和锌阳极副反应的制约。虽然外延生长是通过引导晶体排列来稳定Zn阳极的有效策略,但暴露的晶体和电解质之间的直接接触会导致严重的寄生反应。在这里,我们提出了一种选择性蚀刻策略在锌阳极上(表示为ACE-Zn),优先暴露(101)平面,其具有很强的外延生长特性,以促进锌原子的稳定致密堆积。值得注意的是,(101)平面还促进了ZnS固体电解质界面(SEI)的形成。这种ZnS SEI具有高亲水性和超薄结构,有助于提高离子转移速率,并使Zn阳极与水相关的副反应隔离。因此,ACE-Zn对称电池在0.5 mAh cm - 2和0.5 mA cm - 2下的循环寿命达到了令人印象深刻的4920小时,并且在3500次循环中平均库仑效率(CE)高达99.93%。此外,V-EG//ACE-Zn纽扣电池在10 A g−1下的循环寿命延长了7600次。我们相信这种“一石二鸟”的策略将为纹理化优先平面和构建SEI来稳定Zn阳极提供新的见解。
期刊介绍:
Energy Storage Materials is a global interdisciplinary journal dedicated to sharing scientific and technological advancements in materials and devices for advanced energy storage and related energy conversion, such as in metal-O2 batteries. The journal features comprehensive research articles, including full papers and short communications, as well as authoritative feature articles and reviews by leading experts in the field.
Energy Storage Materials covers a wide range of topics, including the synthesis, fabrication, structure, properties, performance, and technological applications of energy storage materials. Additionally, the journal explores strategies, policies, and developments in the field of energy storage materials and devices for sustainable energy.
Published papers are selected based on their scientific and technological significance, their ability to provide valuable new knowledge, and their relevance to the international research community.