Flash Communication: Isonitrile Cyclization and Indole Tautomerization at a Tucked-in Iron Complex

IF 2.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-01-24 DOI:10.1021/acs.organomet.4c0050510.1021/acs.organomet.4c00505

Joseph A. Zurakowski, Logan J. Taylor and Marcus W. Drover*,

引用次数: 0

Abstract

Treatment of a tucked-in iron(II) diphosphine complex with 2,6-dimethylphenylisonitrile (CN–Xyl) results in cyclization to afford a pair of iron(II) indole tautomers. This reaction outcome contrasts with that of a structurally analogous acyclic iron(II)-methyl complex, which shows no reaction with CN–Xyl. The structure and onward reactivity of these Fe-bound N-heterocycles are assessed experimentally and computationally.

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.