Surface properties and electrochemical synthesis of carbazole derivative polymers

IF 2.2 4区 化学 Q2 Engineering
Aysel Aydın Kocaeren, Beyza Uzun
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引用次数: 0

Abstract

In this study, carbazole-derived polymers were synthesized on ITO (indium tin oxide)-coated PET (Polyethylene terephthalate) via electrochemical reactions and conductivity measurements of the resulting polymeric films depending on temperature were actualized via four-point probe system. Their characterization processes were carried out by UV, FT-IR, NMR, TG-DTG, SEM analyses. Spectroelectrochemical measurements were performed for investigating their electrohromic properties. Homopolymer (P-6C) of carbazole-derived monomer as well as copolymer with thiophene were obtained by electrochemical polymerization method. Based on the CV measurements taken, the resulting copolymer film had good stability on the electrode surface. According to the thermal analysis of the homopolymer, its final degradation temperature was 297 °C and its residue amount at 800 °C was calculated as 18%. Comparisons of conductivity measurements were made depending on the temperature of the polymer films (25, 50 and 90 °C). The electrical conductivity values of the thiophene-carbazole derivative copolymer (6C-T) were decreased depending on the temperature (13.7 S/cm at 25 °C, 1.99 × 10–2 S/cm at 90 °C). The conductivity of carbazole derivative homopolymer product (P-6C) was recorded to increase 10 times with increasing temperature. In the SEM image of P-6C a large and small, non-homogeneous surface with rounded corners was observed. Also, in the SEM image of the copolymer with thiophene (6C-T), small structures with rounded corners originating from thiophene and a non-homogeneous flat surface were seen. As a result, it has been revealed that the copolymer obtained from thiophene and carbazole derivatived compound could be used as a component in electronic devices due to its high conductivity value.

Graphical Abstract

Abstract Image

咔唑衍生物聚合物的表面性质及电化学合成
在本研究中,通过电化学反应在ITO(氧化铟锡)涂层PET(聚对苯二甲酸乙二醇酯)上合成了咔唑衍生聚合物,并通过四点探针系统实现了聚合物薄膜随温度变化的电导率测量。采用紫外光谱、红外光谱、核磁共振、TG-DTG、扫描电镜对其进行了表征。采用光谱电化学方法对其电致变色性能进行了研究。采用电化学聚合法制备了咔唑衍生单体的均聚物(P-6C)以及与噻吩的共聚物。所得共聚物膜在电极表面具有良好的稳定性。根据对均聚物的热分析,其最终降解温度为297℃,800℃时的残留量为18%。根据聚合物薄膜的温度(25,50和90°C)进行电导率测量的比较。噻吩-咔唑衍生物共聚物(6C-T)的电导率随温度的升高而降低(25℃时为13.7 S/cm, 90℃时为1.99 × 10-2 S/cm)。咔唑衍生物均聚物(P-6C)的电导率随温度升高而提高10倍。在P-6C的SEM图像中,观察到一个大而小的、不均匀的圆角表面。此外,在与噻吩共聚物(6C-T)的SEM图像中,可以看到源自噻吩的圆角小结构和非均匀的平面。结果表明,噻吩与咔唑衍生物的共聚物具有较高的电导率,可作为电子器件的组成部分。图形抽象
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来源期刊
Chemical Papers
Chemical Papers Chemical Engineering-General Chemical Engineering
CiteScore
3.30
自引率
4.50%
发文量
590
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
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