Effect of the Electrostatic Charge on the Hydrogen Production by Oxidation of Nanoaluminum

IF 1.1 4区 化学 Q4 CHEMISTRY, PHYSICAL
M. Yu. Ubozhenko, O. N. Morozova, O. B. Kudryashova
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引用次数: 0

Abstract

In the field of hydrogen energy production, submicron powders and nanopowders of aluminum are of particular interest, since they are highly reactive towards aqueous solutions at ambient temperature and pressure in the absence or in the presence of minor amounts of activating agents to generate free hydrogen atoms. Electrostatic spraying can be used to distribute fine powders of aluminum. Currently, applications of electrostatic fields are quite diverse. As a result of electrostatic spraying, agglomerates are broken, and the surface wettability increases. Therefore, to solve the practically important problem of designing a hydrogen generator based on the controlled reaction of aluminum powder with water, preliminary studies of aluminum powder particles are required. In addition, charging of the aluminum particles can affect the oxidation profile and reactivity of the powder. All this indicates the relevance of research on the use of electrostatic field in hydrogen power engineering for new engineering solutions for hydrogen production. The results of the study were used to propose new applications of electrostatic field particularly in the industrial production of hydrogen energy. Highly dispersed aluminum powders were used as the object of research. The work is aimed at finding the optimal parameters for hydrogen generation in the reaction of finely dispersed aluminum powders with aqueous solutions. Experimental studies of pressure and temperature variation during electrostatic deposition of finely dispersed aluminum powders on the surface of a high-temperature reactor are presented.

Abstract Image

静电电荷对纳米铝氧化制氢的影响
在氢能源生产领域,亚微米粉末和纳米铝粉末是特别感兴趣的,因为它们在环境温度和压力下,在没有或存在少量活化剂的情况下,对水溶液具有高度反应性,以产生游离氢原子。静电喷涂可用于铝的细粉分布。目前,静电场的应用非常广泛。由于静电喷涂,团聚体被打破,表面润湿性增加。因此,为了解决设计基于铝粉与水的可控反应的制氢装置这一现实重要问题,需要对铝粉颗粒进行初步研究。此外,铝颗粒的充注会影响粉末的氧化分布和反应性。这些都表明,研究静电场在氢动力工程中的应用对制氢的新工程解决方案具有重要意义。利用研究结果提出了静电场在氢能工业生产中的新应用。以高度分散的铝粉为研究对象。本研究的目的是寻找细分散铝粉与水溶液反应产氢的最佳参数。对高温反应器表面静电沉积精细分散铝粉过程中的压力和温度变化进行了实验研究。
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来源期刊
Doklady Physical Chemistry
Doklady Physical Chemistry 化学-物理化学
CiteScore
1.50
自引率
0.00%
发文量
9
审稿时长
6-12 weeks
期刊介绍: Doklady Physical Chemistry is a monthly journal containing English translations of current Russian research in physical chemistry from the Physical Chemistry sections of the Doklady Akademii Nauk (Proceedings of the Russian Academy of Sciences). The journal publishes the most significant new research in physical chemistry being done in Russia, thus ensuring its scientific priority. Doklady Physical Chemistry presents short preliminary accounts of the application of the state-of-the-art physical chemistry ideas and methods to the study of organic and inorganic compounds and macromolecules; polymeric, inorganic and composite materials as well as corresponding processes. The journal is intended for scientists in all fields of chemistry and in interdisciplinary sciences.
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