Reduced graphene oxide loaded with sodium anthraquinone-2-sulfonate on functionalized carbon cloth for excellent electrochemical performance

IF 2.2 4区 化学 Q2 Engineering
Yan Lin, Yu Ren, Xiaoyun Lin
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引用次数: 0

Abstract

Reduced graphene oxide (RGO) loaded with sodium anthraquinone-2-sulfonate (AQS) was prepared using one-pot hydrothermal synthesis. The phase, composition and structure of the prepared materials were characterized by transmission electron microscope (TEM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and powder X-ray diffraction (XRD). The AQS, RGO and AQS/RGO on functionalized carbon cloth (FCC) electrodes were established. The performance of AQS/FCC, RGO/FCC and AQS/RGO/FCC were tested by galvanostatic charge–discharge (GCD), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The specific capacitance (Cs) of AQS/FCC, RGO/FCC and AQS/RGO/FCC is 9.29, 194.8 and 402.5 F g−1 at the current density (Cd) of 0.5 A g−1, respectively. After 1000 cycles of charging and discharging, the capacity retention of AQS/RGO/FCC remained at 92.6%. Therefore, the AQS/RGO/FCC electrode exhibits excellent rate performance, excellent charging and discharging performance and cycling stability in supercapacitors (SCs).

采用一锅水热合成法制备了负载蒽醌-2-磺酸钠(AQS)的还原氧化石墨烯(RGO)。透射电子显微镜(TEM)、能量色散 X 射线光谱(EDS)、X 射线光电子能谱(XPS)和粉末 X 射线衍射(XRD)对所制备材料的相貌、组成和结构进行了表征。建立了功能化碳布(FCC)电极上的 AQS、RGO 和 AQS/RGO。通过电静电充放电(GCD)、循环伏安法(CV)和电化学阻抗谱(EIS)测试了 AQS/FCC、RGO/FCC 和 AQS/RGO/FCC 的性能。在电流密度(Cd)为 0.5 A g-1 时,AQS/FCC、RGO/FCC 和 AQS/RGO/FCC 的比电容(Cs)分别为 9.29、194.8 和 402.5 F g-1。经过 1000 次充放电循环后,AQS/RGO/FCC 的容量保持率仍为 92.6%。因此,AQS/RGO/FCC 电极在超级电容器(SC)中表现出优异的速率性能、充放电性能和循环稳定性。
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来源期刊
Chemical Papers
Chemical Papers Chemical Engineering-General Chemical Engineering
CiteScore
3.30
自引率
4.50%
发文量
590
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
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