Masking of iron and other interferences during the spectrophotometric analysis of aluminum from soil samples using Alizarin Red S.

IF 1.3 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Turkish Journal of Chemistry Pub Date : 2024-09-17 eCollection Date: 2025-01-01 DOI:10.55730/1300-0527.3713
Hafiz Zain Ul Aabidin, Muhammad Inam Ul Hassan, Tariq Yasin, Muhammad Zubair Rahim, Ahsan Amin Bhatti, Hamayun Imtiaz, Asif Raza
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引用次数: 0

Abstract

In whole-rock geochemical analysis, the quantification of aluminum in geological samples is performed using different analytical techniques including UV-Vis spectrophotometry. During the spectrophotometric analysis of aluminum utilizing Alizarin Red S, iron causes significant interference, leading to inaccurate measurements of the amount of aluminum in the sample. In cases where leached or processed samples contain titanium, interference is also observed. However, appropriate masking agents can remove these interferences. In this study, various masking agents including Tiron, oxalic acid, ascorbic acid, and thioglycolic acid were utilized for the masking of iron. Among these masking agents, ascorbic acid proved to be the best candidate for masking iron. A simple and efficient method was then developed for the masking of iron with the optimization of parameters including concentration of ascorbic acid and reaction time. With this technique, 2 mL of ascorbic acid (10%) can mask iron at up to 3000 ppm in aliquots. Moreover, titanium interference is not observed with this method when the titanium concentration in the aliquot is below 100 ppm. This method was subsequently applied to geological samples and the results were compared to those of atomic absorption spectroscopy. Most samples can easily be analyzed for aluminum by utilizing this masking technique and circumventing interference problems.

茜素红S对土壤样品中铝分光光度分析中铁和其它干扰的屏蔽作用。
在全岩地球化学分析中,铝在地质样品中的定量使用不同的分析技术,包括紫外可见分光光度法。在利用茜素红S对铝进行分光光度分析时,铁会引起明显的干扰,导致样品中铝含量的测量不准确。在浸出或处理的样品含有钛的情况下,也观察到干扰。然而,适当的掩蔽剂可以消除这些干扰。在本研究中,各种掩蔽剂包括铁、草酸、抗坏血酸和巯基乙酸对铁进行掩蔽。在这些掩蔽剂中,抗坏血酸被证明是掩蔽铁的最佳候选者。通过对抗坏血酸浓度和反应时间等参数的优化,建立了一种简单有效的铁掩蔽方法。使用这种技术,2ml的抗坏血酸(10%)可以在等分中掩盖高达3000ppm的铁。当等分液中钛的浓度低于100ppm时,不存在钛的干扰现象。随后将该方法应用于地质样品,并与原子吸收光谱的结果进行了比较。大多数样品可以很容易地分析铝利用这种掩蔽技术和规避干扰问题。
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来源期刊
Turkish Journal of Chemistry
Turkish Journal of Chemistry 化学-工程:化工
CiteScore
2.40
自引率
7.10%
发文量
87
审稿时长
3 months
期刊介绍: The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK). The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings. The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities. The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields. All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.
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