{"title":"Shale Gas Production and CO2 Storage of CO2-ESGR Based on the Stress–Strain–Sorption Behavior of Shale","authors":"Hongzhang Wang, Junping Zhou*, Xuefu Xian, Shifeng Tian, Zhiqiang Dong, Chenghao Xu, Nianjie Kuang, Yifan Peng, Chenye Guo and Huaquan Jiang, ","doi":"10.1021/acs.energyfuels.5c0048910.1021/acs.energyfuels.5c00489","DOIUrl":null,"url":null,"abstract":"<p >The CO<sub>2</sub>-enhanced shale gas recovery (CO<sub>2</sub>-ESGR) technique is a promising method for enhancing shale gas production and sequestering of CO<sub>2</sub>. In this study, a two-component gas flow model in shale reservoirs considering the stress–strain–sorption behavior of shale during the CO<sub>2</sub>-ESGR process was developed. Using this model, the impact of the parameters of the ratio of Langmuir volume of CO<sub>2</sub> (<i></i><math><msub><mi>V</mi><mrow><mi>L</mi><mo>,</mo><mi>C</mi><msub><mi>O</mi><mn>2</mn></msub></mrow></msub></math>) to Langmuir volume of CH<sub>4</sub> (<i></i><math><msub><mi>V</mi><mrow><mi>L</mi><mo>,</mo><mi>C</mi><msub><mi>H</mi><mn>4</mn></msub></mrow></msub></math>), initial reservoir pressure, CO<sub>2</sub> injection rate (<i>R</i><sub>i</sub>), and the staring time of CO<sub>2</sub> injection (<i>T</i><sub>s,i</sub>) on the CO<sub>2</sub>-ESGR process was analyzed by numerical simulation. The results indicate that the sustained reduction in reservoir porosity and permeability during primary production is dominated by the effect of effective stress changes. Following CO<sub>2</sub> injection, reservoir porosity and permeability decrease rapidly in the CO<sub>2</sub> sweep region mainly due to the CO<sub>2</sub>/CH<sub>4</sub> adsorption-induced differential swelling, while it is still dominated by effective stress changes outside the CO<sub>2</sub> sweep region. CH<sub>4</sub> production is negatively related to <i></i><math><msub><mi>V</mi><mrow><mi>L</mi><mo>,</mo><mi>C</mi><msub><mi>O</mi><mn>2</mn></msub></mrow></msub><mo>/</mo><msub><mi>V</mi><mrow><mi>L</mi><mo>,</mo><mi>C</mi><msub><mi>H</mi><mn>4</mn></msub></mrow></msub></math> and <i>T</i><sub>s,i</sub>, while positively related to the initial reservoir pressure and <i>R</i><sub>i</sub>. The CO<sub>2</sub> storage volume is positively related to <i></i><math><msub><mi>V</mi><mrow><mi>L</mi><mo>,</mo><mi>C</mi><msub><mi>O</mi><mn>2</mn></msub></mrow></msub><mo>/</mo><msub><mi>V</mi><mrow><mi>L</mi><mo>,</mo><mi>C</mi><msub><mi>H</mi><mn>4</mn></msub></mrow></msub></math>, <i>R</i><sub>i</sub>, and <i>T</i><sub>s,i</sub>, while shows no significant correlation with the initial reservoir pressure. These findings offer valuable insights for parameter optimization of the CO<sub>2</sub>-ESGR process.</p>","PeriodicalId":35,"journal":{"name":"Energy & Fuels","volume":"39 11","pages":"5406–5418 5406–5418"},"PeriodicalIF":5.2000,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy & Fuels","FirstCategoryId":"5","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.energyfuels.5c00489","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
The CO2-enhanced shale gas recovery (CO2-ESGR) technique is a promising method for enhancing shale gas production and sequestering of CO2. In this study, a two-component gas flow model in shale reservoirs considering the stress–strain–sorption behavior of shale during the CO2-ESGR process was developed. Using this model, the impact of the parameters of the ratio of Langmuir volume of CO2 () to Langmuir volume of CH4 (), initial reservoir pressure, CO2 injection rate (Ri), and the staring time of CO2 injection (Ts,i) on the CO2-ESGR process was analyzed by numerical simulation. The results indicate that the sustained reduction in reservoir porosity and permeability during primary production is dominated by the effect of effective stress changes. Following CO2 injection, reservoir porosity and permeability decrease rapidly in the CO2 sweep region mainly due to the CO2/CH4 adsorption-induced differential swelling, while it is still dominated by effective stress changes outside the CO2 sweep region. CH4 production is negatively related to and Ts,i, while positively related to the initial reservoir pressure and Ri. The CO2 storage volume is positively related to , Ri, and Ts,i, while shows no significant correlation with the initial reservoir pressure. These findings offer valuable insights for parameter optimization of the CO2-ESGR process.
期刊介绍:
Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.