Linking Cyanometallate [Fe2Co2] Squares into One-Dimensional Chains via Benzoquinones

IF 3.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Crystal Growth & Design Pub Date : 2025-02-26 DOI:10.1021/acs.cgd.5c0009110.1021/acs.cgd.5c00091

Jiong Yang, Jing Xi, Shihao Liu, Jia-Quan Huang, Yi-Fei Deng*, Xiaoyong Chang and Yuan-Zhu Zhang*,

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引用次数: 0

Abstract

The construction of functional cyanometallate clusters connected by secondary bridges is a highly sought-after area of research in chemistry and materials science. Our investigation has led to the discovery of three novel compounds, {[(Tp*)Fe(CN)₃Co(bpy)]₂(μ-CA)·4MeOH}_n (1), {[(Tp*^Me)Fe(CN)₃Co(dpa)]₂(μ-CA)}_n (2), and {[(Tp*^Me)Fe(CN)₃Co(bpy)]₂(μ-dhbq)}_n (3) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate, Tp*^Me = hydrotris(3,4,5-trimethylpyrazolyl)borate, H₂CA = 2,5-dichloro-3,6-dihydroxy-2,5-cyclohexadiene-1,4-dione, dhbq = 2,5-dihydroxy-1,4-benzoquinone, bpy = 2,2′-bipyridyl, and dpa = 2,2′-dipyridylamine). These compounds were synthesized via a self-assembly reaction of the [(Tp^R)Fe^III(CN)₃]⁻ building block, Co(II) salts, and chelating ligands of bpy or dpa, followed by addition of benzoquinone dianions. X-ray crystallographic analyses revealed that 1–3 exhibited similar structures, where cyanide-bridged [Fe₂Co₂] squares are connected by benzoquinones to form a one-dimensional chain. Magnetic studies demonstrated a ferromagnetic interaction between the cyanide-bridged Fe and Co ions but an antiferromagnetic interaction between the benzoquinone-bridged Co–Co pairs. Notably, compounds 2 and 3 displayed metamagnetic behaviors with antiferromagnetic orderings below 4 K.

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来源期刊

Crystal Growth & Design 化学-材料科学：综合

CiteScore

6.30

自引率

10.50%

发文量

650

审稿时长

1.9 months

期刊介绍： The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials. Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.