Photoelectrochemical Synthesis of Adipic Acid by Selective Oxidation of Cyclohexanone (Adv. Energy Mater. 11/2025)

IF 24.4 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Advanced Energy Materials Pub Date : 2025-03-17 DOI:10.1002/aenm.202570053

Shanshan Zhang, Lan Luo, Jiangrong Yang, Wangsong Chen, Yucong Miao, Ruikang Zhang, Zhenhua Li, Rengui Li, Mingfei Shao, Xue Duan

引用次数: 0

Abstract

Photoelectrochemical Syntheses

In article number 2405052, Ruikang Zhang, Zhenhua Li, Mingfei Shao, and co-workers first reported a photoelectrochemical strategy to achieve the selective oxidation of cyclohexanone to adipic acid using a cooperative Ni(OH)₂/TiO₂ photoanode with H₂O as oxygen source. The new Ni^2+δ─OH* reactive center was in situ generated on a Ni(OH)₂/TiO₂ photoanode under illumination, which significantly facilitates the activation of C_α─H and the subsequent C─C cleavage to produce adipic acid.

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通过选择性氧化环己酮光电化学合成己二酸（Adv. Energy Mater. 11/2025）

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS

CiteScore

41.90

自引率

4.00%

发文量

889

审稿时长

1.4 months

期刊介绍： Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.