Rücktitelbild: Diastereoselective Polypseudorotaxane Formation with Planar Chiral Pillar[5]arenes via Co-crystallization Processes (Angew. Chem. 12/2025)

Kiichi Yasuzawa, Dr. Keisuke Wada, Prof. Dr. Shixin Fa, Prof. Dr. Yuuya Nagata, Dr. Kenichi Kato, Dr. Shunsuke Ohtani, Prof. Dr. Motohiro Mizuno, Prof. Dr. Tomoki Ogoshi
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Abstract

Diastereoselective polypseudorotaxane formation via co-crystallization of stereodynamic planar chiral pillar[5]arene and polyethylene glycol is reported by Tomoki Ogoshi et al. in their Research Article (e202420115). In the image, the bracelet represents the polypseudorotaxane, with blue and red stones depicting the pS and pR forms of the pillar[5]arene ring, respectively. The crystals between the stones imply the crystallization method. As the number of stones increases, the possible combinations multiply, making selection more difficult, but ultimately, you will find the bracelet that suits you best.

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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