Electrodeposition of metals into nano/micropores of templates: a type of electrochemistry under confinement (review)

IF 2.6 4区化学 Q3 ELECTROCHEMISTRY

Journal of Solid State Electrochemistry Pub Date : 2024-11-28 DOI:10.1007/s10008-024-06118-8

D. A. Bograchev, T. B. Kabanova, A. D. Davydov

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Abstract

Electrodeposition of metals into nanopores of templates represents a crucial area of study within the field of confinement-controlled electrochemistry. This review addresses the templated synthesis of nanocomposites (nonmetallic hard templates with one-dimensional cylindrical nanopores filled with metal or semiconductor) and single nanowires and nanotubes obtained by template dissolution. The focus is on the influence of electrochemical conditions such as electrolyte composition, electrodeposition regimes, and template characteristics on the morphological and physical properties of the resulting nanostructures. Additionally, this review introduces the theoretical modeling of mass transfer in templated electrodeposition, which is critical for understanding and optimizing the pore-filling processes and the uniformity of nanostructure formation. The potential applications of these nanostructures in fields such as electronics, optoelectronics, and catalysis are also discussed, highlighting their significant implications for advancing nanotechnology and materials science.

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金属在模板纳米/微孔中的电沉积：一种约束下的电化学（综述）

将金属电沉积到模板的纳米孔中是约束控制电化学领域的一个重要研究领域。本文综述了模板法合成纳米复合材料（具有一维圆柱形纳米孔填充金属或半导体的非金属硬模板）和通过模板溶解获得的单纳米线和纳米管。重点是电化学条件的影响，如电解质组成、电沉积制度和模板特征对所得到的纳米结构的形态和物理性质的影响。此外，本文还介绍了模板电沉积中传质的理论建模，这对于理解和优化孔隙填充过程和纳米结构形成的均匀性至关重要。本文还讨论了这些纳米结构在电子、光电子和催化等领域的潜在应用，强调了它们对推进纳米技术和材料科学的重要意义。

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来源期刊

Journal of Solid State Electrochemistry 工程技术-电化学

CiteScore

4.80

自引率

4.00%

发文量

227

审稿时长

4.1 months

期刊介绍： The Journal of Solid State Electrochemistry is devoted to all aspects of solid-state chemistry and solid-state physics in electrochemistry. The Journal of Solid State Electrochemistry publishes papers on all aspects of electrochemistry of solid compounds, including experimental and theoretical, basic and applied work. It equally publishes papers on the thermodynamics and kinetics of electrochemical reactions if at least one actively participating phase is solid. Also of interest are articles on the transport of ions and electrons in solids whenever these processes are relevant to electrochemical reactions and on the use of solid-state electrochemical reactions in the analysis of solids and their surfaces. The journal covers solid-state electrochemistry and focusses on the following fields: mechanisms of solid-state electrochemical reactions, semiconductor electrochemistry, electrochemical batteries, accumulators and fuel cells, electrochemical mineral leaching, galvanic metal plating, electrochemical potential memory devices, solid-state electrochemical sensors, ion and electron transport in solid materials and polymers, electrocatalysis, photoelectrochemistry, corrosion of solid materials, solid-state electroanalysis, electrochemical machining of materials, electrochromism and electrochromic devices, new electrochemical solid-state synthesis. The Journal of Solid State Electrochemistry makes the professional in research and industry aware of this swift progress and its importance for future developments and success in the above-mentioned fields.