Caiyan Tian , Luisa Speicher , Hao Song , Norman Ahlmann , Sebastian Brandt , Guanghui Niu , Joachim Franzke
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引用次数: 0
Abstract
Not only Helium and Argon but also Neon, Krypton, and Xenon can be used as plasma gas for a discharge applied for soft ionization with similar ionization efficiency, although it is clear that each of the excited and even ionized states of Xe is lower than the ion energy of N2+ or H3O+. In this work, the discharge behavior of these plasmas both inside and outside of the capillary was investigated to study the mechanisms of soft ionization. Two discharge modes were found. In He- and Ne2.0 kV -FμTP, the ionization wave of N2+ is mainly responsible for the propagation of excitation and ionization inside the capillary while the ionization wave of noble gas ions plays the role in Ar-, Kr- and Xe-FμTP. With an increase of the applied voltage, Ne2.5 kV -FμTP fulfils characteristics of both categories. All the measured ionization waves stop in the vicinity of the capillary outlet. For all plasmas, the propagation of excitation wave is tracked in ambient surrounding, which hints that an ionization wave is propagating outside the capillary. It is assumed that ions species of air components such as N2+, O2+ and H3O+ are generated in the ambient surrounding. The ionization wave of these ions continues supporting the propagation of the excitation wave.
期刊介绍:
Spectrochimica Acta Part B: Atomic Spectroscopy, is intended for the rapid publication of both original work and reviews in the following fields:
Atomic Emission (AES), Atomic Absorption (AAS) and Atomic Fluorescence (AFS) spectroscopy;
Mass Spectrometry (MS) for inorganic analysis covering Spark Source (SS-MS), Inductively Coupled Plasma (ICP-MS), Glow Discharge (GD-MS), and Secondary Ion Mass Spectrometry (SIMS).
Laser induced atomic spectroscopy for inorganic analysis, including non-linear optical laser spectroscopy, covering Laser Enhanced Ionization (LEI), Laser Induced Fluorescence (LIF), Resonance Ionization Spectroscopy (RIS) and Resonance Ionization Mass Spectrometry (RIMS); Laser Induced Breakdown Spectroscopy (LIBS); Cavity Ringdown Spectroscopy (CRDS), Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy (LA-ICP-AES) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS).
X-ray spectrometry, X-ray Optics and Microanalysis, including X-ray fluorescence spectrometry (XRF) and related techniques, in particular Total-reflection X-ray Fluorescence Spectrometry (TXRF), and Synchrotron Radiation-excited Total reflection XRF (SR-TXRF).
Manuscripts dealing with (i) fundamentals, (ii) methodology development, (iii)instrumentation, and (iv) applications, can be submitted for publication.