Icephobic and antisoiling performance of PDMS coating filling with inert silicon oil after prolonged outdoor exposure

IF 2.3 4区 材料科学 Q2 CHEMISTRY, APPLIED
Tu Shuhua, Zheng Qinwen, Zhang Jing, Feng Jie
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Abstract

Recently, much attention has been paid to the icephobic property of slippery lubricant-infused surfaces, but little attention has been paid to their antisoiling property. In this work, we prepared polydimethylsiloxane (PDMS) coatings by using methyltriacetoxysilane (TM-003) as a crosslinking agent and filling with a certain amount of inert silicone oil. We systematically studied the icephobic and antisoiling performances of these PDMS coatings by placing them outdoors for 1–2 months. Ice-adhesion strength test confirmed that the coating surface filled with inert silicone oil was more icephobic and had a better icephobic effect as the amount of inert silicone oil increased. EDS mapping confirmed that after outdoor exposure for 1–2 months, a small amount of dust deposited on the coating surface, which could be removed mostly by water rinsing and wind. The ice-adhesion strengths of the coating surface increased with the time of outdoor exposure increasing but decreased after several cycles of icing/deicing and finally stabilized at a certain level. XPS characterization confirmed that a small amount of dust was embedded in the coating surface. This work firstly confirmed that if the air was not clear, dust particles in the air would adhere to the coating and the icephobic properties of the coating would deteriorate irreversibly to some extent.

Abstract Image

填充惰性硅油的PDMS涂层在长时间室外暴露后的疏冰和防污性能
近年来,人们对注入润滑油的光滑表面的疏冰性能关注较多,但对其防污性能关注较少。本文以甲基三乙酰氧基硅烷(TM-003)为交联剂,填充一定量的惰性硅油,制备聚二甲基硅氧烷(PDMS)涂料。我们系统地研究了这些PDMS涂料的疏冰和防污性能,并将其放置在户外1-2个月。冰附强度试验证实,惰性硅油填充的涂层表面憎冰性更强,并且随着惰性硅油用量的增加,憎冰效果更好。EDS测绘证实,在室外暴露1-2个月后,涂层表面有少量灰尘沉积,大部分可以通过水冲洗和风去除。涂层表面的粘冰强度随室外暴露时间的增加而增加,但经过多次冰/除冰循环后,粘冰强度下降,并最终稳定在一定水平。XPS表征证实涂层表面嵌有少量粉尘。这项工作首先证实,如果空气不清澈,空气中的粉尘颗粒会附着在涂层上,涂层的疏冰性能会在一定程度上不可逆地恶化。
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来源期刊
Journal of Coatings Technology and Research
Journal of Coatings Technology and Research 工程技术-材料科学:膜
CiteScore
4.30
自引率
8.70%
发文量
130
审稿时长
2.5 months
期刊介绍: Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.
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