Endohedral Metallofullerenes: Unveiling Synthesis Mechanisms and Advancing Photoelectric Energy Conversion Applications

IF 8.6 2区化学 Q1 Chemistry

Topics in Current Chemistry Pub Date : 2025-03-14 DOI:10.1007/s41061-025-00500-4

Weifeng Chen, Meiyan Huang, Mixue Wu, Yizhu Lei

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Abstract

Endohedral metallofullerenes (EMFs) have garnered significant attention for their distinctive properties and potential integration into cutting-edge photoelectric devices. This review provides a comprehensive overview of recent advancements in EMF synthesis, highlighting the novel “self-driven carbon atom implantation” approach that sheds new light on the underlying mechanisms of EMF formation. The discussion delves into pivotal challenges related to yield optimization and purification processes, addressing current limitations and the imperative need for scalable synthesis and improved stability. Furthermore, the review explores the burgeoning applications of EMFs in photoelectric energy conversion, focusing on their capacity to enhance the efficiency of photovoltaic devices. Their unique electronic structures and tunable energy levels are highlighted as key factors contributing to improved charge separation and overall performance. In conclusion, this review offers a forward-looking perspective on interdisciplinary research avenues essential for harnessing the full potential of EMFs. It underscores the need for collaborative efforts across materials science, chemistry, and nanotechnology to overcome existing hurdles and to integrate EMFs into next-generation energy conversion technologies, thereby paving the way for more efficient and sustainable energy solutions.

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内源性金属富勒烯：揭示合成机制和推进光电能量转换应用

内嵌金属富勒烯（EMFs）因其独特的性能和潜在的集成到尖端光电器件中而受到广泛关注。本文综述了电磁场合成的最新进展，重点介绍了新型“自驱动碳原子植入”方法，该方法为电磁场形成的潜在机制提供了新的思路。讨论深入到与产率优化和纯化工艺相关的关键挑战，解决当前的局限性以及可扩展合成和提高稳定性的迫切需要。此外，本文还探讨了电磁场在光电能量转换中的新兴应用，重点介绍了它们提高光伏器件效率的能力。它们独特的电子结构和可调谐的能级被强调为促进电荷分离和整体性能的关键因素。总之，这篇综述为充分利用电磁场的潜力提供了一个前瞻性的跨学科研究途径。它强调了跨材料科学、化学和纳米技术的合作努力的必要性，以克服现有的障碍，并将电磁场集成到下一代能量转换技术中，从而为更有效和可持续的能源解决方案铺平道路。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Topics in Current Chemistry 化学-化学综合

CiteScore

11.70

自引率

1.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science. Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community. In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.