Self-catalyzed growth of Co–N codoped carbon nanotubes for advanced multi-heterointerface engineering in hierarchical carbonaceous microwave absorbers

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Yan Guo, Hongsen Long, Ziqi Wang, Shijun Luo, Lei Xu, Chuntai Liu, Changyu Shen, Hu Liu
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Abstract

Recently, the rational construction of hierarchical multi-heterointerfaces microstructure is becoming an extremely attractive strategy to obtain lightweight and excellent metal–organic frameworks (MOFs) based electromagnetic wave (EMW) absorbing materials. Herein, hierarchical MOF derived Co–N codoped carbon nanotube modified carbon foam (Co-NC@CF) with multi-heterointerfaces was fabricated via simple in-situ growth of ZIF-67 MOFs nanosheets on the surface of three-dimensional (3D) melamine foam (MF), followed by a pyrolytic self-catalyzed process, where the nitrogenous organic linkers of ZIF-67 were successfully converted into Co nanoparticle encapsulated N-doped carbon nanotubes. In addition to the synergetic effect of dielectric − magnetic dual-loss mechanism, the hierarchical heterogeneous and porous structure of Co-NC@CF also shows good impedance matching, multiple polarization loss, and multiple reflection and scattering. Furthermore, the numerous N-doped atoms and defects are vitally important for the enhancement of interfacial/dipole polarization, thereby enhancing the EMW dissipation properties. As a result, the EMW absorption performance of the prepared Co-NC@CF can be effectively tuned by changing the temperature of pyrolytic autocatalytic Co–N codoped carbon nanotube (CNTs), and the Co-NC@CF calcinated at 800 °C (Co-NC@CF-800) displays the strongest EMW absorption capability with a minimum reflection loss (RLmin) value of − 51.56 dB at a thickness of 2.25 mm at 14.96 GHz with only 5 wt% filler loading, and the maximum effective absorption bandwidth (EABmax) also reaches 6.88 GHz ranging from 11.12 to 18 GHz. These excellent electromagnetic properties can make Co-NC@CF eligible to be a great promising candidate for high-performance EMW absorbing materials, and this work will provide inspiration more or less for the design of hierarchical heterogeneous absorbing materials in the future.

多层碳质微波吸收器中先进多异质界面工程中Co-N共掺杂碳纳米管的自催化生长
近年来,合理构建层次化的多异质界面微结构已成为获得轻质、优异的金属有机框架基电磁波吸收材料的一种极具吸引力的策略。本文通过在三维(3D)三聚氰胺泡沫(MF)表面原位生长ZIF-67 MOF纳米片,并通过热解自催化过程,成功地将ZIF-67的含氮有机连接体转化为Co纳米颗粒封装的n掺杂碳纳米管,制备了具有多异质界面的分层MOF衍生Co- n共掺杂碳纳米管改性碳泡沫(Co-NC@CF)。除了介电-磁双损耗机制的协同作用外,Co-NC@CF的层次化非均质多孔结构也表现出良好的阻抗匹配、多次极化损耗、多次反射散射等特性。此外,大量的n掺杂原子和缺陷对于增强界面/偶极极化至关重要,从而提高EMW耗散性能。结果表明,通过改变热解自催化Co-N共掺杂碳纳米管(CNTs)的温度,可以有效地调节制备的Co-NC@CF的EMW吸收性能,在800℃下煅烧的Co-NC@CF (Co-NC@CF-800)在14.96 GHz时表现出最强的EMW吸收能力,在2.25 mm厚度处的最小反射损失(RLmin)值为- 51.56 dB,填充量仅为5 wt%;最大有效吸收带宽(EABmax)也达到6.88 GHz,范围为11.12 ~ 18 GHz。这些优异的电磁性能使Co-NC@CF有资格成为高性能EMW吸波材料的一个很有前途的候选材料,并且该工作将为未来分层非均相吸波材料的设计提供或多或少的灵感。
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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