MARVEL analysis of high-resolution spectra of ozone (16O3)

IF 2.3 3区物理与天体物理 Q2 OPTICS

Journal of Quantitative Spectroscopy & Radiative Transfer Pub Date : 2025-03-09 DOI:10.1016/j.jqsrt.2025.109399

Apoorva Upadhyay , Tibor Furtenbacher , Armando N. Perri , Charles A. Bowesman , Eamon K. Conway , Katy L. Chubb , Alec Owens , Caitlin P. Dobney , Ella Bowen , Daniel Broner , Victor Ciobanu , Katherina Gelborova , Sam Livsey , Damilola Magbagbeola , Madhushree Manjunatha , Tom Mitchell , David Morohunfola , Emaan Wijayakoon , Sophie Winter , Jonathan Tennyson

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引用次数: 0

Abstract

Accurate rotation-vibration (ro-vibrational) energy levels of the main isotopologue of ozone (¹⁶O₃) in its ground electronic

\tilde{X}^{1} A_{1}

state are determined by performing MARVEL (Measured Active Rotation Vibration Energy Levels) analysis on measured line positions from 29 sources of data published in scientific literature. A total of 50276 ro-vibrational transitions are considered yielding 13664 MARVEL energy levels of ¹⁶O₃ with their associated uncertainties. The maximum values of the energy and rotational angular momentum quantum number in the MARVEL dataset are 8167.33 cm⁻¹ and

J = 67

respectively. Variational nuclear motion calculations of ¹⁶O₃ energy levels are performed and subsequently used to assess and validate the MARVEL results. Comparisons with alternative data compilations based on effective Hamiltonians are also shown.

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来源期刊

Journal of Quantitative Spectroscopy & Radiative Transfer 物理-光谱学

CiteScore

5.30

自引率

21.70%

发文量

273

审稿时长

58 days

期刊介绍： Papers with the following subject areas are suitable for publication in the Journal of Quantitative Spectroscopy and Radiative Transfer: - Theoretical and experimental aspects of the spectra of atoms, molecules, ions, and plasmas. - Spectral lineshape studies including models and computational algorithms. - Atmospheric spectroscopy. - Theoretical and experimental aspects of light scattering. - Application of light scattering in particle characterization and remote sensing. - Application of light scattering in biological sciences and medicine. - Radiative transfer in absorbing, emitting, and scattering media. - Radiative transfer in stochastic media.