Environmental Toxicity of Cement Nanocomposites Reinforced with Carbon Nanotubes.

Abstract

The addition of carbon nanotubes (CNTs) to cement matrix brings multiple beneficial effects ranging from improving mechanical and physical properties to the creation of smart materials. When subjected to an erosive environment or as end-of-life waste, mortars with CNT addition might get released into the environment and come in contact with surface waters. The assessment of the environmental impact of mortars reinforced with carbon nanotubes is an important factor concerning their sustainability, as it has not yet been addressed in the literature. The presented paper aims to assess the water toxicity of cement mortars with various dosages of 0.05 wt.%, 0.1 wt.%, and 0.2 wt.% of carbon nanotube. The effect of the quality of water dispersion of CNTs was also considered through two sonication times of the suspension: 20 min and 60 min. Tests using indicator organisms, Aliivibrio fischeri, Daphnia magna, and Lemna minor, were conducted on shredded and non-shredded mortars. The results reveal no to low toxicity for all tested mortars under the assumed framework of toxicity assessment. The toxicity results for samples containing CNTs were comparable to those without CNTs, indicating that the toxicity of mortars incorporating CNTs is not greater than that of conventional cement-based materials. The water toxicity of the cement mortars is rather connected with the washing away of the hydration products more than with the presence of carbon nanotubes.