Navid Allahyar, Sibel Yazar, Ayse E. Kurtoglu, Cemal Ozeroglu
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引用次数: 0
Abstract
Uranyl ions (UO₂²⁺) are the form of uranium usually dissolved in water and are radioactive and can cause serious damage to the environment. Adsorption of uranyl ions is a critical method for removing and safely storing radioactive materials that harm the environment. It is also an important tool for combating water and soil contamination, managing nuclear waste and environmental sustainability. Polymer-based composites were developed for this purpose. Polymer-based composites enable the efficient removal of harmful and radioactive uranium compounds from water and soil. Through the incorporation of polymers and fillers (such as zeolite), materials with specific properties capable of adsorbing uranyl ions with high efficiency can be designed. The ratio of the components constituting the composites can be adjusted to optimize the adsorption capacity, as well as the chemical and thermal behaviors. Two composites were created: P(MA-Z50), consisting of ethylene glycol dimethacrylate (EGDM), methacrylic acid (MA), and zeolite, and P(MA-Z75), which contained a higher amount of zeolite. These composites were synthesized at room temperature and analyzed using various techniques such as Fourier transform infrared (FTIR), thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). The study investigated the effects of adsorbent quantity, adsorbate concentration, temperature, time, and pH on adsorption efficiency and capacity. The Langmuir adsorption isotherm provided the best fit for uranium (VI) adsorption. The results showed that rapid adsorption occurred within the first 100 min, with the rate slowing down until equilibrium was reached after 360 min. The pseudo-second-order kinetic model best described the adsorption process.
期刊介绍：
The journal Adsorption provides authoritative information on adsorption and allied fields to scientists, engineers, and technologists throughout the world. The information takes the form of peer-reviewed articles, R&D notes, topical review papers, tutorial papers, book reviews, meeting announcements, and news.
Coverage includes fundamental and practical aspects of adsorption: mathematics, thermodynamics, chemistry, and physics, as well as processes, applications, models engineering, and equipment design.
Among the topics are Adsorbents: new materials, new synthesis techniques, characterization of structure and properties, and applications; Equilibria: novel theories or semi-empirical models, experimental data, and new measurement methods; Kinetics: new models, experimental data, and measurement methods. Processes: chemical, biochemical, environmental, and other applications, purification or bulk separation, fixed bed or moving bed systems, simulations, experiments, and design procedures.
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