Investigation of bismuth doping effect on electrical and thermal properties of n-type PbSnS2

IF 4.3 3区材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Journal of Physics and Chemistry of Solids Pub Date : 2025-03-10 DOI:10.1016/j.jpcs.2025.112655

E.V. Argunov , A.I. Kartsev , E.V. Chernyshova , K.A. Shcherbakova , F.Yu. Bochkanov , E.A. Kolesnikov , M.A. Seredina , Yu.M. Kuznetsov , M.V. Dorokhin , A.V. Zdoroveyshev , V.L. Kurichenko , D.Yu. Karpenkov

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引用次数: 0

Abstract

In this work, we have studied the influence of bismuth on thermoelectric properties of

{Pb}_{(1 - x)} {Bi}_{x} Sn S_{2}

\leq

\leq

0.1). It was demonstrated that the addition of bismuth significantly increases electrical conductivity from 83.5

{Sm}^{- 1}

to 1407

{Sm}^{- 1}

at 750 K. The maximum thermoelectric figure of merit

z T_{m a x} = 0.55

was achieved at 750 K. Furthermore, the mechanisms underlying these improvements were described through density functional theory (DFT) calculations. Our results indicate that the increase in electrical conductivity is linked to modifications in the electronic structure. This study highlights the potential of

{Pb}_{(1 - x)} {Bi}_{x} Sn S_{2}

as an effective thermoelectric material and provides insights into optimizing its properties through strategic doping.

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来源期刊

Journal of Physics and Chemistry of Solids 工程技术-化学综合

CiteScore

7.80

自引率

2.50%

发文量

605

审稿时长

40 days

期刊介绍： The Journal of Physics and Chemistry of Solids is a well-established international medium for publication of archival research in condensed matter and materials sciences. Areas of interest broadly include experimental and theoretical research on electronic, magnetic, spectroscopic and structural properties as well as the statistical mechanics and thermodynamics of materials. The focus is on gaining physical and chemical insight into the properties and potential applications of condensed matter systems. Within the broad scope of the journal, beyond regular contributions, the editors have identified submissions in the following areas of physics and chemistry of solids to be of special current interest to the journal: Low-dimensional systems Exotic states of quantum electron matter including topological phases Energy conversion and storage Interfaces, nanoparticles and catalysts.