Nitrogen and phosphorus dual doped-fluorescent carbon quantum dots: An efficient nanoprobe sensor for sensitive and selective detection of ferric and mercuric ions

IF 4.4 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR
Rajnee Yadav , Vikas Lahariya , Akhilesh Kumar Singh
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引用次数: 0

Abstract

The work uses phosphorous and nitrogen-co-doped carbon quantum dots (PN-CQDs) to present the effective and precise metal ion sensing for Fe (III) and Hg (II) in aqueous environments. Fluorescent PN-CQDs were synthesized using a microwave method with Citrus limetta juice as the carbon source, phosphoric acid (85 %) as the phosphorus source, and ethylenediamine for nitrogen. Structural analysis confirmed 4 nm spherical particles with an amorphous carbon core and rich surface functionalities. XPS revealed 6.63 % phosphorus and 15.48 % nitrogen doping. Optical studies showed excitation-dependent photoluminescence (PL) in the UV–visible range, with maximum emission at 550 nm under 440 nm excitation. The PN-CQDs exhibited a high quantum yield (56 %) and strong photostability under UV and visible light. For heavy metal ion sensing, the PN-CQDs showed high selectivity towards Hg(II) and sensitivity for Fe(III) among other metal ions, achieving nanomolar detection limits (1.35 nM for Fe(III) and 5.23 nM for Hg(II)). The linear response range and low detection limits highlight the potential of PN-CQDs as reliable fluorescent probes for the selective detection of Fe(III) and Hg(II) metal ions. The quenching mechanism was attributed to static quenching through ground state complex formation. The presence of phosphorus and pyridinic-N groups enabled selective Fe(III) and Hg(II) detection in real water samples with reliable recovery rates (96–100 %). These results underscore the high sensitivity and selectivity of PN-CQDs for detecting Fe(III) and Hg(II) ions, making them highly effective for environmental monitoring and bioanalytical applications.

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来源期刊
Inorganic Chemistry Communications
Inorganic Chemistry Communications 化学-无机化学与核化学
CiteScore
5.50
自引率
7.90%
发文量
1013
审稿时长
53 days
期刊介绍: Launched in January 1998, Inorganic Chemistry Communications is an international journal dedicated to the rapid publication of short communications in the major areas of inorganic, organometallic and supramolecular chemistry. Topics include synthetic and reaction chemistry, kinetics and mechanisms of reactions, bioinorganic chemistry, photochemistry and the use of metal and organometallic compounds in stoichiometric and catalytic synthesis or organic compounds.
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