Interaction Parameters of Some Polymers Used in Nuclear Power Plants with Ionizing Radiation, Produced Secondary Radiations and Radiation Damages

IF 4.2 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Ferdi Akman, Hasan Oğul
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Abstract

The primary interactions of polypropylene (PP), poly(vinyl acetate) (PVA), ethylene-vinyl acetate (EVA), polyvinyl chloride (PVC), polychloroprene (CR) and polyurethane (PUR) polymers preferred in the nuclear industry with gamma and neutron radiations, secondary radiations formed after neutron interactions and damages given to polymers by these ionizing radiations are investigated. The gamma interaction parameters Were determined in the photon energy range of 0.03-20 MeV using WinXCOM, GEANT4 and FLUKA methods. Also, energy absorption and exposure buildup factors and Kerma parameters are calculated at different photon energies. To investigate the interactions of the studied polymers with neutron, the effective removal cross-section for fast neutrons with theoretical and the partial neutron rates passing through the studied polymer at 4.5 MeV, 100 eV and 0.025 eV energies are determined with simulation codes. The numbers of secondary gamma-rays and neutrons Were obtained with GEANT4. The Total Ionizing Dose and Displacements per Atom parameters are studied with the help of FLUKA simulation. It is observed that the interaction of PVC polymer with gamma radiation and PP polymer with neutron particles is higher than the others. The secondary radiation from PVC and CR is less. The PP, PVA, and EVA exhibit superior resistance to radiation damage.

Abstract Image

核电厂中某些聚合物与电离辐射的相互作用参数、产生的二次辐射和辐射损伤
研究了核工业中常用的聚丙烯(PP)、聚醋酸乙烯(PVA)、乙烯-醋酸乙烯(EVA)、聚氯乙烯(PVC)、氯丁橡胶(CR)和聚氨酯(PUR)等聚合物与伽马和中子的初次相互作用、中子相互作用后形成的二次辐射以及这些电离辐射对聚合物的损伤。利用WinXCOM、GEANT4和FLUKA方法测定了光子能量在0.03 ~ 20 MeV范围内的γ相互作用参数。计算了不同光子能量下的能量吸收和曝光积累因子及Kerma参数。为了研究所研究的聚合物与中子的相互作用,用模拟程序确定了在4.5 MeV、100 eV和0.025 eV能量下,理论快中子率和部分中子率通过所研究的聚合物的有效去除截面。用GEANT4计算了二次伽马射线和中子的数量。利用FLUKA模拟研究了总电离剂量和每原子位移参数。结果表明,聚氯乙烯聚合物与伽马射线的相互作用和PP聚合物与中子粒子的相互作用较大。PVC和CR的二次辐射较小。PP、PVA和EVA具有优异的抗辐射损伤能力。
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来源期刊
Macromolecular Materials and Engineering
Macromolecular Materials and Engineering 工程技术-材料科学:综合
CiteScore
7.30
自引率
5.10%
发文量
328
审稿时长
1.6 months
期刊介绍: Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications. Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science. The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments. ISSN: 1438-7492 (print). 1439-2054 (online). Readership:Polymer scientists, chemists, physicists, materials scientists, engineers Abstracting and Indexing Information: CAS: Chemical Abstracts Service (ACS) CCR Database (Clarivate Analytics) Chemical Abstracts Service/SciFinder (ACS) Chemistry Server Reaction Center (Clarivate Analytics) ChemWeb (ChemIndustry.com) Chimica Database (Elsevier) COMPENDEX (Elsevier) Current Contents: Physical, Chemical & Earth Sciences (Clarivate Analytics) Directory of Open Access Journals (DOAJ) INSPEC (IET) Journal Citation Reports/Science Edition (Clarivate Analytics) Materials Science & Engineering Database (ProQuest) PASCAL Database (INIST/CNRS) Polymer Library (iSmithers RAPRA) Reaction Citation Index (Clarivate Analytics) Science Citation Index (Clarivate Analytics) Science Citation Index Expanded (Clarivate Analytics) SciTech Premium Collection (ProQuest) SCOPUS (Elsevier) Technology Collection (ProQuest) Web of Science (Clarivate Analytics)
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