{"title":"Green, reusable, efficient aluminium-based metal–organic aerogels for wastewater treatment","authors":"Monty Gulia, Archana Thakur","doi":"10.1007/s13738-024-03165-w","DOIUrl":null,"url":null,"abstract":"<div><p>This study explores the hydrothermal synthesis and characterization of novel, green, reusable aluminium metal–organic aerogels (Al-MOAs) designed for wastewater treatment. Using aluminium nitrate nonahydrate as metal precursor, glutaric acid and phloroglucinol as organic linkers, two aluminium metal–organic aerogels [Al-MOA (1) and Al-MOA (2)] were synthesized followed by thermal. The successful synthesis of aerogels was confirmed via IR, FE-SEM, EDX, and powder XRD analyses. The FE-SEM analysis revealed microporous surface favorable for Victoria blue dye adsorption and catalytic applications in phenol degradation. The effects of key parameters such as pH, time, and the concentration of Al-MOA (1) and (2) on dye adsorption efficiency were studied. The Al-MOAs also demonstrated catalytic efficiencies in phenol degradation indicating potential in wastewater treatment. Optimal adsorption efficiency was observed at 3 pH demonstrating 99% dye removal by Al-MOA (1). Additionally, in dye adsorption, Al-MOA (1) and (2) highlighting the potential for multiple reuse cycles, thus offering a sustainable, green, cost-effective approach towards wastewater treatment. This study contributes to the development of advanced, non-toxic, insoluble, reusable, sustainable solutions for wastewater treatment utilizing metal–organic aerogels.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":676,"journal":{"name":"Journal of the Iranian Chemical Society","volume":"22 3","pages":"517 - 533"},"PeriodicalIF":2.2000,"publicationDate":"2025-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13738-024-03165-w.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Iranian Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s13738-024-03165-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
This study explores the hydrothermal synthesis and characterization of novel, green, reusable aluminium metal–organic aerogels (Al-MOAs) designed for wastewater treatment. Using aluminium nitrate nonahydrate as metal precursor, glutaric acid and phloroglucinol as organic linkers, two aluminium metal–organic aerogels [Al-MOA (1) and Al-MOA (2)] were synthesized followed by thermal. The successful synthesis of aerogels was confirmed via IR, FE-SEM, EDX, and powder XRD analyses. The FE-SEM analysis revealed microporous surface favorable for Victoria blue dye adsorption and catalytic applications in phenol degradation. The effects of key parameters such as pH, time, and the concentration of Al-MOA (1) and (2) on dye adsorption efficiency were studied. The Al-MOAs also demonstrated catalytic efficiencies in phenol degradation indicating potential in wastewater treatment. Optimal adsorption efficiency was observed at 3 pH demonstrating 99% dye removal by Al-MOA (1). Additionally, in dye adsorption, Al-MOA (1) and (2) highlighting the potential for multiple reuse cycles, thus offering a sustainable, green, cost-effective approach towards wastewater treatment. This study contributes to the development of advanced, non-toxic, insoluble, reusable, sustainable solutions for wastewater treatment utilizing metal–organic aerogels.
期刊介绍:
JICS is an international journal covering general fields of chemistry. JICS welcomes high quality original papers in English dealing with experimental, theoretical and applied research related to all branches of chemistry. These include the fields of analytical, inorganic, organic and physical chemistry as well as the chemical biology area. Review articles discussing specific areas of chemistry of current chemical or biological importance are also published. JICS ensures visibility of your research results to a worldwide audience in science. You are kindly invited to submit your manuscript to the Editor-in-Chief or Regional Editor. All contributions in the form of original papers or short communications will be peer reviewed and published free of charge after acceptance.