{"title":"Highly Shear-Thickening Electrolyte with Impact Resistance for Flexible Aqueous Zinc-Ion Batteries","authors":"Lijie Luo, Ling Jiang, Qi Song, Qing Chen, Wenjie Huang, Zhiquan Hu, Hongming Chen, Shuo Huang* and Yongjun Chen*, ","doi":"10.1021/acssuschemeng.4c0997910.1021/acssuschemeng.4c09979","DOIUrl":null,"url":null,"abstract":"<p >Aqueous zinc-ion batteries (ZIBs) are desirable for large-scale energy storage due to their high energy density, cost-effectiveness, and eco-friendliness. However, the enhancement of their durability under impact remains a major challenge since traditional liquid electrolytes are prone to leakage when subjected to severe shocks or impacts. In this study, a novel shear-thickening electrolyte was reported by integrating starch with Zn(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub> electrolyte. Under normal conditions, this electrolyte behaves like a conventional liquid electrolyte with excellent ionic conductivity, low viscosity, and high fluidity. While upon exposure to external force stimuli, the liquid electrolyte can change to a solid. Moreover, the starch molecules have strong interactions with Zn<sup>2+</sup>, promoting the epitaxial electroplating of Zn on the anode and effectively suppressing dendrite formation. The ZIBs fabricated based on this shear-thickening electrolyte possess good electrochemical performance and stability, with a capacity retention rate of 96.5% after 3000 cycles at 2 A g<sup>–1</sup>. More interestingly, the assembled AlVO/CC-50%/Zn flexible battery demonstrates high capacity retention after bending at angles of up to 90°. This shear- thickening electrolyte prevents the battery from damage caused by external force, thereby significantly boosting the impact resistance and the flexible properties of ZIBs.</p>","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"13 9","pages":"3660–3668 3660–3668"},"PeriodicalIF":7.1000,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sustainable Chemistry & Engineering","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acssuschemeng.4c09979","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Aqueous zinc-ion batteries (ZIBs) are desirable for large-scale energy storage due to their high energy density, cost-effectiveness, and eco-friendliness. However, the enhancement of their durability under impact remains a major challenge since traditional liquid electrolytes are prone to leakage when subjected to severe shocks or impacts. In this study, a novel shear-thickening electrolyte was reported by integrating starch with Zn(CF3SO3)2 electrolyte. Under normal conditions, this electrolyte behaves like a conventional liquid electrolyte with excellent ionic conductivity, low viscosity, and high fluidity. While upon exposure to external force stimuli, the liquid electrolyte can change to a solid. Moreover, the starch molecules have strong interactions with Zn2+, promoting the epitaxial electroplating of Zn on the anode and effectively suppressing dendrite formation. The ZIBs fabricated based on this shear-thickening electrolyte possess good electrochemical performance and stability, with a capacity retention rate of 96.5% after 3000 cycles at 2 A g–1. More interestingly, the assembled AlVO/CC-50%/Zn flexible battery demonstrates high capacity retention after bending at angles of up to 90°. This shear- thickening electrolyte prevents the battery from damage caused by external force, thereby significantly boosting the impact resistance and the flexible properties of ZIBs.
期刊介绍:
ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment.
The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.