Multigram-Scale Synthetic Routes to Solvent-Free Common Secondary Dialkylphosphines and Chlorodialkylphosphines

IF 2.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-02-20 DOI:10.1021/acs.organomet.4c0050810.1021/acs.organomet.4c00508

Amanda A. Fogh, Sara Belazregue, Andrew E. Ashley* and F. Mark Chadwick*,

引用次数: 0

Abstract

Secondary dialkylphosphines and chlorodialkylphosphines are some of the most common starting points in ligand synthesis; however, sourcing these synthons can be troublesome. In this paper, we present scalable synthetic routes to the iso-propyl, tert-butyl, and cyclohexyl derivatives. Detailed experimental procedures are given to allow for ease of synthesis.

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.